FIELD: chemistry.
SUBSTANCE: invention relates to fibres from polycrystalline corundum, essentially consisting of corundum and an oxide of elements of the main subgroups of groups I and II, which can be used in producing fabric and composite materials. The fibres are produced using a method which involves adding nucleating seeds and a precursor of an oxide of elements of the main subgroups of groups I and II to aluminium chlorohydrate, adding a water-soluble polymer, subsequent spinning of fibres from said mixture and annealing said fibres at temperature 1100°C or higher. The nucleating seeds used are ultra-finely dispersed diaspore, haematite or corundum, which are added to the spinning solution in amount of 0.1-10 wt %. The oxides of elements of main subgroups of groups I and II are in the fibres in amount of 0.01-0.5 wt %. Crystallites of said corundum fibres are characterised by the following grain-size distribution: from 0 to 0.06 mcm (34%), from 0.06 to 0.122 mcm (55%) and from 0.122 to 0.3 mcm (11%).
EFFECT: fibres have improved mechanical properties.
4 cl, 1 ex
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Authors
Dates
2012-10-27—Published
2007-09-08—Filed