FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing perchloroethylene by catalytic hydrodechlorination of carbon tetrachloride with hydrogen. The disclosed method is characterised by that the process is carried out in a solution of NaOH, in the presence of a palladium catalyst on a carbon support, at temperature of 110-130°C and pressure in the system of 0.9-1.1 MPa.
EFFECT: use of the present method increases catalyst efficiency and prolongs service life thereof.
1 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF TREATING ORGANCHLORINE WASTES CONTAINING CARBON TETRACHLORIDE | 2012 |
|
RU2478089C1 |
| METHOD OF PRODUCING SODIUM FORMATE | 2012 |
|
RU2484080C1 |
| METHOD OF CONVERTING ORGANOCHLORIDE WASTES TO METHYL CHLORIDE | 2008 |
|
RU2379278C1 |
| METHOD OF PROCESSING POLYCHLOROORGANIC WASTE | 2005 |
|
RU2315030C2 |
| METHOD OF OBTAINING MONOCHLORACETIC ACID | 2008 |
|
RU2391331C2 |
| METHOD OF PRODUCING TETRACHLOROETHYLENE | 2010 |
|
RU2434837C1 |
| METHOD OF PROCESSING CARBON TETRACHLORIDE INTO METHYL CHLORIDE | 2005 |
|
RU2298542C1 |
| METHOD OF HYDRODECHLORINATION OF CHLORAROMATIC COMPOUNDS AND CATALYST FOR METHOD REALISATION | 2006 |
|
RU2339606C2 |
| BIMETALLIC CATALYST FOR LIQUID-PHASE SELECTIVE HYDROGENATION OF ACETYLENIC HYDROCARBONS AND METHOD FOR ITS PRODUCTION | 2022 |
|
RU2786218C1 |
| METHOD OF SYNTHESIS OF VINYL CHLORIDE | 1993 |
|
RU2072976C1 |
