FIELD: chemistry.
SUBSTANCE: glass having lead sulphide nanoparticles (PbS) is used in laser equipment as clarifying filters, specifically solid-state passive shutters for near-infrared lasers which are sued in ophthalmology, fibre-optic communication systems, optical location and range finding. Spectral absorption and clarification at wavelength 1.5 mcm is achieved by forming in a glass matrix PbS nanoparticles with a defined size (5.5-5.9 nm) as a result of heat treatment of the glass. The glass has components in the following ratios, wt %: SiO2 50.0-54.5; Na2O 6.0-7.5; ZnO 12.5-15.0; PbO 6.5-8.5; S 3.5-4.0; AlF3 3.0-3.5; K2O 10.0-15.0.
EFFECT: forming lead sulphide nanocrystals with size of 5,5-5,9 nm in a silicate glass matrix to provide spectral absorption and clarification at wavelength 1,5 mcm.
2 tbl
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Authors
Dates
2013-06-20—Published
2011-10-18—Filed