CATALYST FOR OXIDATIVE DECOMPOSITION OF ORGANOCHLORINE COMPOUNDS IN GASES AND METHOD FOR PRODUCTION THEREOF Russian patent published in 2013 - IPC B01J23/52 B01J23/46 B01J21/06 B01J37/03 B01D53/70 

Abstract RU 2488441 C1

FIELD: chemistry.

SUBSTANCE: invention relates to chemical treatment of gas emissions, particularly a catalyst for oxidative decomposition of organochlorine compounds and a method of producing said catalyst. The invention describes a catalyst for oxidative decomposition of organochlorine compounds in gases which contain gold, rhodium and titanium oxide, with the following ratio of components, wt %: Au - 0.001-1; Rh - 0.05-3; titanium oxide (TiO2) - the balance, and a method of producing said catalyst by depositing a rhodium compound onto titanium oxide in a suspension at room temperature and intense stirring, followed by heating the suspension at temperature of 70-98°C, passing hydrogen over the suspension while stirring, first at temperature of 70-98°C and then at room temperature, followed by addition of a solution of a gold compound to the obtained suspension while stirring and at room temperature under an hydrogen-containing atmosphere.

EFFECT: high catalyst activity and selectivity of oxidation to HCl, wherein catalysts of the disclosed composition enable to form less than 5 ppm CO during oxidation of both humid air (1,6 vol %) and technical-grade air (air water content of 0,26 vol %).

2 cl, 3 tbl, 11 ex

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RU 2 488 441 C1

Authors

Kucherov Aleksej Viktorovich

Kirichenko Ol'Ga Alekseevna

Kustov Leonid Modestovich

Dates

2013-07-27Published

2012-07-18Filed