FIELD: chemistry.
SUBSTANCE: ceramic aluminium-cobalt oxide pigment is prepared based on nano-sized mesoporous synthetic xonotlite by preparing a reaction solution containing calcium (II), silicate and a high-molecular weight surfactant of the class of quaternary ammonium salts; calcium hydrosilicate is precipitated from the solution while stirring. An aluminium-cobalt phase is then added to the prepared suspension; the formed precursor is separated, washed, dried at 60°C on air and annealed at 800-960°C. The aluminium-cobalt phase is obtained by extracting and concentrating cobalt (II) ions and aluminium from aqueous solutions of salts thereof using monocarboxylic acids and subsequent preparation of an aqueous emulsion of a mixture of cobalt and aluminium carboxylates.
EFFECT: invention enables to obtain environmentally safe, intensely coloured aluminium-cobalt oxide pigments with weight-average particle size of 200-70 nm, having high covering power.
8 cl, 4 ex
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Authors
Dates
2013-09-20—Published
2010-11-12—Filed