FIELD: chemistry.
SUBSTANCE: compositions for making articles contain a basic polymer, at least one compound of formula and , where X is selected from a group consisting of O, S and NH; Y, A and B are independently selected from a group consisting of N and CH; D, E and F are independently selected from a group consisting of CH, N, O and S; the symbol ---- denotes a single bond or double bond; and R1, R2 and R3 are independently selected from a group consisting of H, electron acceptor groups and electron donor groups and transition metals, at least one transition metal in a positive oxidation state, where said metal is present in the composition in amount of 10-400 ppm, wherein said compound is present in amount of about 0.10-10 wt % of the weight of said composition. In other versions of the invention, the compounds are used as oxygen absorbents and in compositions and articles which prevent oxygen penetration.
EFFECT: obtaining basically transparent materials, having high oxygen binding capacity.
82 cl, 5 dwg, 12 ex
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Authors
Dates
2013-12-27—Published
2008-05-09—Filed