FIELD: chemistry.
SUBSTANCE: invention relates to catalysis. Described is a method of preparing a catalyst for cracking oil fractions, which involves conducting ion exchange for cations of rare-earth elements and ammonia on zeolite NaY, ultra-stabilisation of the zeolite in a medium of water vapour, mixing the zeolite with a matrix, components of which are bentonite clay, aluminium hydroxide and amorphous aluminosilicate, obtaining a composition, spray drying the obtained composition, followed by calcination to obtain a catalyst, wherein ultra-stabilisation of the zeolite is carried out thrice: first and second ultra-stabilisation at steps of preparing the zeolite before mixing with components of the matrix, and third ultra-stabilisation of the zeolite is carried out in the catalyst composition; ion exchange for cations of rare-earth elements and ammonia is carried out four times to obtain ultra-stable zeolite Y with content of sodium oxide of not more than 0.6 wt %, oxides of rare-earth elements of 0.5-5.5 wt %, and content of oxides of rare-earth elements in the catalyst of 0.05-1.1 wt %.
EFFECT: high catalyst activity.
2 tbl, 4 ex
Title | Year | Author | Number |
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MICROPSHERICAL CATALYST FOR OIL FRACTIONS CRACKING AND METHOD OF ITS MAKING | 2011 |
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METHOD OF PREPARATION OF CRAKING CATALYST WITH ALKALINE EARTH ELEMENTS | 2016 |
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RU2300420C2 |
METHOD OF PREPARATION OF ULTRASTRABLE ZEOLITE Y | 2016 |
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MICRO-SPHERICAL CATALYST FOR INCREASING YIELD OF CATALYTIC CRACKING GASOLINE AND METHOD FOR ITS PREPARATION | 2021 |
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RU2789407C1 |
MICROSPHERICAL CATALYST FOR OIL FRACTIONS CRACKING | 2018 |
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RU2673811C1 |
CATALYST FOR INTERMOLECULAR HYDROGEN TRANSFER REACTIONS AND PREPARATION METHOD THEREOF | 2015 |
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RU2599720C1 |
MICROSPHERICAL CATALYST FOR REDUCING SULPHUR CONTENT IN CRACKED GASOLINE AND METHOD FOR PRODUCTION THEREOF | 2011 |
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RU2472586C1 |
Authors
Dates
2014-03-20—Published
2013-01-09—Filed