METHOD OF DETERMINING GLUTATHIONE IN STANDARD TEST AQUEOUS SOLUTIONS VIA CYCLIC VOLTAMMETRY ON GRAPHITE ELECTRODE, MODIFIED WITH COLLOIDAL SILVER PARTICLES Russian patent published in 2014 - IPC G01N27/06 

Abstract RU 2510016 C1

FIELD: chemistry.

SUBSTANCE: method of determining glutathione involves determination by cyclic voltammetry, wherein there is electrocatalytic oxidation of glutathione on a graphite electrode modified with silver particles. The method according to the invention involves modifying graphite electrodes with colloidal silver particles from a silver sol for 300 s at electrolysis potential of -1.0 V, followed by recording anodic maxima of electrooxidation of glutathione on an anodic curve with potential sweep rate of 100 mV/s on a background of 0.1 M NaOH solution in the potential range from -1.0 V to 1.0 V; concentration of glutathione is determined from the height of anodic maxima of current versus voltage curves in the potential range from 0.30 V to 0.60 V relative a saturated silver chloride electrode by standard addition method.

EFFECT: high sensitivity of the method of determining glutathione.

2 ex, 1 tbl, 2 dwg

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RU 2 510 016 C1

Authors

Perevezentseva Dar'Ja Olegovna

Gorchakov Ehduard Vladimirovich

Dates

2014-03-20Published

2012-11-06Filed