FIELD: chemistry.
SUBSTANCE: method of producing highly pure cadmium carbonate involves treating aqueous cadmium nitrate solution, purified in advance, with aqueous ammonia solution, followed by carbonisation of the intermediate product - cadmium ammoniate - with carbon dioxide gas and separating the end product, wherein 15-30% aqueous cadmium nitrate solution is treated with 25-30% aqueous ammonia solution with volume ratio of ammonia solution to cadmium nitrate solution of (0.62-0.65):1. Carbonisation is carried out by passing carbon dioxide gas through the reaction mass at a rate of 0.10-0.28 l/min. The separated cadmium carbonate precipitate is washed with distilled water and dried at 100-110°C.
EFFECT: invention enables to obtain highly pure cadmium carbonate with high content of the basic substance and high output, which is suitable for producing optical glass.
2 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING PURE CALCIUM CARBONATE | 2013 |
|
RU2532189C1 |
METHOD OF OBTAINING SODIUM CARBONATE | 2013 |
|
RU2540659C1 |
METHOD OF PRODUCING HIGH-PURITY CALCIUM CARBONATE | 2009 |
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RU2412906C1 |
METHOD OF PRODUCING HIGH-PURITY STRONTIUM CARBONATE | 2009 |
|
RU2412116C1 |
METHOD OF CADMIUM NITRATE PURIFICATION | 2012 |
|
RU2493103C1 |
ABSORBENT FOR REMOVAL OF CARBON DIOXIDE FROM GAS MIXTURES | 2002 |
|
RU2244587C2 |
METHOD OF PREPARING CATALYST FOR PRODUCING METHANOL | 1990 |
|
RU1774556C |
METHOD FOR PRODUCTION OF COPPER, ZINC, NICKEL AND COBALT BASIC CARBONATES AND OXIDES | 1991 |
|
RU2043301C1 |
METHOD OF PRODUCING HIGH-PURITY CALCIUM FLUORIDE | 2009 |
|
RU2424188C1 |
Authors
Dates
2014-07-10—Published
2013-02-14—Filed