FIELD: chemistry.
SUBSTANCE: group of inventions can be used in the production of catalysts, in particular, for the selective NOx reduction. A catalytic composition contains at least one oxide on a carrier, consisting of zirconium oxide, or titanium oxide, or mixed zirconium and titanium oxide, or of zirconium oxide and an oxide of at least one oxide of other element, selected from praseodymium, lanthanum, neodymium and yttrium, applied on a silicon oxide-based carrier. After burning at 900°C for 4 hours the oxide on the carrier has a shape of particles applied on the carrier. The size of the said particles constitutes not more than 5 nm, if the oxide on the carrier is obtained on the basis of zirconium oxide, not more than 10 nm, if the oxide on the carrier is obtained on the basis of titanium oxide, and not more than 8 nm, if the oxide on the carrier is obtained on the basis of mixed zirconium and titanium oxide. After burning at 1000°C for 4 hours the size of the particles constitutes not more than 7 nm, if the oxide on the carrier is obtained on the basis of zirconium oxide, not more than 19 nm, if the oxide on the carrier is obtained on the basis of titanium oxide, and not more than 10 nm, if the oxide on the carrier is obtained on the basis of mixed zirconium and titanium oxide.
EFFECT: invention makes it possible to reduce the size of the particles in the catalytic composition, their aggregation and sintering at high temperature.
10 cl, 1 tbl, 9 ex
Title |
Year |
Author |
Number |
COMPOSITION BASED ON ZIRCONIUM OXIDE, TITANIUM OXIDE OR MIXED ZIRCONIUM AND TITANIUM OXIDE, DEPOSITED ON SILICON OXIDE SUPPORT, METHODS OF PRODUCING SAID COMPOSITION AND USE THEREOF AS CATALYST |
2009 |
- Verd'E Stefan
- Krin'Er Gijom
- Ifra Simon
- Zhorzhe Koehl'O Markesh Ruj
|
RU2448908C1 |
COMPOSITION BASED ON ZIRCONIUM OXIDE, TITANIUM OXIDE OR MIXED ZIRCONIUM AND TITANIUM OXIDE, APPLIED ON ALUMINIUM OXIDE OR ALUMINIUM OXYHYDROXIDE CARRIER, METHODS OF ITS OBTAINING AND ITS APPLICATION AS CATALYST |
2009 |
- Verd'E Stefan
- Krin'Er Gijom
- Ifra Simon
- Zhorzhe Koehl'O Markesh Ruj
|
RU2476381C2 |
MIXED OXIDE BASED ON CERIUM AND ZIRCONIUM |
2017 |
- Jorge Coelho Marques, Rui Miguel
- Ifrah, Simon
- Chabert, Boris
|
RU2753046C2 |
NANOMETRIC CERIUM OXIDE-BASED COMPOSITION ON HIGH REDUCING POWER SUPPORT, PREPARATION METHOD THEREOF AND USE AS CATALYST |
2007 |
- Fazhardi Frank
- Verd'E Stefan
|
RU2411995C2 |
MIXED CERIUM AND ZIRCONIUM OXIDES |
2016 |
- Ifrah, Simon
- Li, Wei
- Buissette, Valerie
- Denaire, Stephane
- Marques, Rui
|
RU2707888C1 |
ZIRCONIUM ACID HYDROXIDE |
2017 |
- Stefenson, Khejzel
- Chepurna, Irina
- Kharris, Debora Dzhejn
- Skejpens, Devid
|
RU2743207C2 |
ZIRCONIUM OXIDE DISPERSION, METHOD FOR PRODUCTION THEREOF AND RESIN COMPOSITION CONTAINING SAME |
2009 |
- Nakagava Keniti
- Morita Takanori
|
RU2509728C2 |
ZIRCONIUM OXIDE DISPERSION AND METHOD OF OBTAINING IT |
2009 |
- Nakagava Keniti
- Morita Takanori
|
RU2529219C2 |
COMPOSITION BASED ON ZIRCONIUM OXIDE, YTTRIUM OXIDE AND TUNGSTEN OXIDE, METHOD OF PRODUCTION AND USE AS CATALYST OR CATALYST SUPPORT |
2009 |
- Ljarshe Oliv'E
- Roar Ehmmanjuehl'
- Verd'E Stefan
- Krin'Er Gijom
- Kharris Debora
- Brehdshou Khiter
|
RU2440299C1 |
COMPOSITION, BASED ON ZIRCONIUM OXIDE AND AT LEAST ONE OXIDE OF RARE-EARTH ELEMENT, DIFFERENT FROM CERIUM, WITH PARTICULAR POROSITY, METHODS OF THEREOF OBTAINING AND THEREOF APPLICATION IN CATALYSTS |
2011 |
|
RU2570810C2 |