FIELD: chemistry.
SUBSTANCE: invention relates to a method of obtaining a catalyst of selective hydration of organic compounds, including soaking reticulated foam polyurethane with a slip, containing more than 30 wt % of aluminium α-oxide with further drying at a temperature of 100…120°C, annealing at a temperature of 1050…1070°C, further multiple soaking of the obtained highly porous cellular carrier with a solution of alumina sol to 6…10 wt % of the carrier weight, drying at a temperature of 100…120°C, annealing at a temperature of 550…600°C, processing with a palladium nitrate solution, drying at a temperature not higher than 120°C and annealing at a temperature of 450…500°C, reduction of the obtained palladium oxide on the carrier with molecular hydrogen in nitrogen to metallic palladium with the weight content not more than 0.5 wt % at a temperature of 50…55°C, whose surface is after that modified with palladium nanoparticles by a radiation chemical method.
EFFECT: increase of the catalyst service term, elimination of a stage of filtration of the target product from the catalyst and obtaining the pure target product.
4 ex
| Title | Year | Author | Number | 
|---|---|---|---|
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| METHOD OF MAKING HIGHLY POROUS CELLULAR CERAMIC ARTICLES | 2011 | 
 | RU2475464C2 | 
| COMPOSITION OF CHARGE FOR HIGH-POROSITY CERAMIC MATERIAL WITH LATTICED-CELLULAR STRUCTURE | 2013 | 
 | RU2525396C1 | 
| METHOD FOR CATALYTIC LIQUID-PHASE HYDROGENATION OF 2',4,'4-NRINITROBENZANILIDE | 2005 | 
 | RU2288911C1 | 
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Authors
Dates
2014-11-10—Published
2013-05-16—Filed