FIELD: chemistry.
SUBSTANCE: invention relates to the field of organic chemistry, in particular, to a method of obtaining N, N'-bis-(2-hydroxyethyl)tetrathiadiazacycloalkanes of the general formula (1) 1a n=3, 1b n=4, 1c n=5, 1d n=6. The essence of the method consists in the interaction of a formaldehyde mixture and α,ω-dithiol with 2-aminoethanol with the molar ratio of formaldehyde : α,ω-dithiol : 2-aminoethanol = 2:1:1 at room temperature (~20°C) and atmospheric pressure for 2.5-3.5 h. The invention also relates to the application of the formula (1) compounds as means with fungicidal activity for fighting fungal diseases of agricultural cultures.
EFFECT: obtaining the formula (1) compounds, possessing the fungicidal activity against Bipolaris sorokiniana and Rhizoctonia solani.
2 cl, 5 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING 1,6-BIS-(1,5,3-DITHIAZEPAN-3-YL)-2,5-DISULPHANYLHEXANE, POSSESSING FUNGICIDAL ACTIVITY | 2013 |
|
RU2547266C2 |
METHOD OF PRODUCING N-ALKYL-N,N-BIS[Ω-(PIPERIDIN-1-YL)ALKADIIN-1-YL]AMINES EXHIBITING FUNGICIDAL ACTIVITY | 2019 |
|
RU2734488C1 |
N,N'-DI(ALKADINYL)DIAZACYCLOALKANES AND METHOD OF PRODUCING N,N'-DI(ALKADINYL)DIAZACYCLOALKANES EXHIBITING FUNGICIDAL ACTIVITY WITH RESPECT TO FUNGI BIPOLARIS SOROKINIANA AND RHIZOCTONIA SOLANI | 2019 |
|
RU2727138C1 |
METHOD OF OBTAINING 3,3'-(3,6-DIOXAOCTANE-1,8-DIYL)BIS-1,5,3-DITHIAZEPINANE AND ITS APPLICATION AS AGENT WITH FUNGICIDAL ACTIVITY | 2013 |
|
RU2547267C2 |
2-PHENYLTHIOMETHYL SUBSTITUTED 1,3-DIKETONES AND DIMETHYLMALONATE - AGENT HAVING FUNGICIDAL ACTIVITY | 2015 |
|
RU2616603C2 |
METHOD OF OBTAINING 5-METHOXYCARBONYL-1,3-DITHIANE, POSSESSING FUNGICIDAL ACTIVITY | 2012 |
|
RU2536205C2 |
PRODUCTION METHOD FOR 3-[(PHENYLSULFENYL)METHYL]PENTANE-2,4-DIONE SHOWING A FUNGICIDAL ACTIVITY | 2015 |
|
RU2615155C2 |
3,7-DITIA-1,5-DIAZABICYCLO[3.3.0]OCTANE N-COORDINATED BY METHYLIODID - WATER-SOLUBLE AGENT WITH FUNGICIDAL ACTIVITY | 2010 |
|
RU2442329C1 |
METHOD OF PRODUCING 3-[1-(1-ADAMANTYL)ETHYL]-1,5,3-DITHIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT | 2014 |
|
RU2574292C1 |
METHOD OF PRODUCING WATER-SOLUBLE 2,5-AMINOMETHYLATED PYRROLE DERIVATIVES EXHIBITING FUNGISTATIC ACTION | 2017 |
|
RU2705400C2 |
Authors
Dates
2015-02-20—Published
2013-01-29—Filed