METHOD OF OBTAINING 1,6-BIS-(1,5,3-DITHIAZEPAN-3-YL)-2,5-DISULPHANYLHEXANE, POSSESSING FUNGICIDAL ACTIVITY Russian patent published in 2015 - IPC C07D285/36 A01N43/00 A01P3/00 

Abstract RU 2547266 C2

FIELD: chemistry.

SUBSTANCE: invention relates to method of obtaining 1,6-bis-(1,5,3-dithiazepan-3-yl)-2,5-disulphanylhexane of formula (1), possessing fungicidal activity against Botrytis cinerea and Rhizoctonia solani. Essence of method lies in interaction of mixture of 1,2-ethanedithiol and formaldehyde with water solution of ammonium salts NH4X (X=F, Br, OAc, NO3, 1/2SO4) with molar ratio HS(CH2)2SH:CH2O:NH4X=3:6:2 at room temperature (~20°C) and atmospheric pressure for 5-7 h.

EFFECT: output of 1,6-bis-(1,5,3-dithiazepan-3-yl)-2,5-disulphanylhexane of general formula (1) depending on applied ammonium salts (NH4X) constitutes 31-67%.

2 cl, 2 tbl, 1 ex

Similar patents RU2547266C2

Title Year Author Number
METHOD OF OBTAINING 3,3'-(3,6-DIOXAOCTANE-1,8-DIYL)BIS-1,5,3-DITHIAZEPINANE AND ITS APPLICATION AS AGENT WITH FUNGICIDAL ACTIVITY 2013
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Zajnullin Radik Anvarovich
  • Galimzjanova Nailja Fauatovna
  • Rakhimova Elena Borisovna
  • Ismagilov Rinat Arfikovich
RU2547267C2
METHOD OF OBTAINING N, N'-BIS-(2-HYDROXYETHYL)TETRATHIADIAZACYCLOALKANES, DEMONSTRATING FUNGICIDAL ACTIVITY 2013
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Khabibullina Guzel' Razhapovna
  • Akhmetova Vnira Rakhimovna
  • Galimzjanova Nailja Fautovna
  • Khalilov Leonard Mukhibovich
  • Tjumkina Tat'Jana Viktorovna
RU2541793C2
METHOD OF PRODUCING 3-[1-(1-ADAMANTYL)ETHYL]-1,5,3-DITHIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT 2014
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Galimzjanova Nailja Fauatovna
  • Rakhimova Elena Borisovna
  • Ismagilov Rinat Arfikovich
RU2574292C1
METHOD OF PRODUCING 3,3'-BI-1,5,3-DITHIAZEPINANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT 2010
  • Dzhemilev Usein Memetovich
  • Murzakova Natalija Nail'Evna
  • Khabibullina Guzel' Razhapovna
  • Akhmetova Vnira Rakhimovna
  • Tjumkina Tat'Jana Viktorovna
  • Galimzjanova Nailja Fuatovna
  • Ibragimov Askhat Gabdrakhmanovich
RU2448107C2
METHOD OF OBTAINING BIS-(1,5,3-DITHIAZEPINAN-3-YL)ETHANE AND ITS APPLICATION AS MEDICATION WITH ANTIFUNGAL ACTIVITY 2013
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Zajnullin Radik Anvarovich
  • Galimzjanova Nailja Fauatovna
  • Rakhimova Elena Borisovna
  • Ismagilov Rinat Arfikovich
RU2541791C2
3,7-DITIA-1,5-DIAZABICYCLO[3.3.0]OCTANE N-COORDINATED BY METHYLIODID - WATER-SOLUBLE AGENT WITH FUNGICIDAL ACTIVITY 2010
  • Dzhemilev Usein Memetovich
  • Murzakova Natalija Nail'Evna
  • Khabibullina Guzel' Razhapovna
  • Akhmetova Vnira Rakhimovna
  • Galimzjanova Nailja Fuatovna
  • Ibragimov Askhat Gabdrakhmanovich
RU2442329C1
METHOD OF PRODUCING N-ALKYL-N,N-BIS[Ω-(PIPERIDIN-1-YL)ALKADIIN-1-YL]AMINES EXHIBITING FUNGICIDAL ACTIVITY 2019
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Khabibullina Guzel Razhapovna
  • Zajnullina Firuza Timiryanovna
  • Galimzyanova Nailya Fauatovna
RU2734488C1
METHOD OF PRODUCING 3-(1-ADAMANTYL)-1,5,3-DITIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT 2014
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Galimzjanova Nailja Fauatovna
  • Rakhimova Elena Borisovna
  • Ismagilov Rinat Arfikovich
RU2584692C2
METHOD OF OBTAINING 5-(1,5,3-DITHIAZEPAN-3-YL)QUINOLINE AND ITS APPLICATION AS MEANS WITH FUNGICIDAL ACTIVITY 2014
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Galimzjanova Nailja Fauatovna
  • Rakhimova Elena Borisovna
  • Vasil'Eva Inna Vladimirovna
RU2565783C1
AGENT AGAINST CROP FUNGAL DISEASES 2011
  • Akhmetova Vnira Rakhimovna
  • Minnebaev Azamat Bareevich
  • Rakhimova Elena Borisovna
  • Abdullin Marat Ibragimovich
  • Galimzjanova Nailja Fauatovna
  • Melent'Ev Aleksandr Ivanovich
RU2483539C1

RU 2 547 266 C2

Authors

Dzhemilev Usein Memetovich

Akhmetova Vnira Rakhimovna

Khabibullina Guzel' Razhapovna

Ibragimov Askhat Gabdrakhmanovich

Galimzjanova Nailja Fauatovna

Khalilov Leonard Mukhibovich

Janybin Vasilij Mikhajlovich

Dates

2015-04-10Published

2013-01-29Filed