FIELD: chemistry.
SUBSTANCE: group of inventions relates to catalytic materials for chemical reactors. Said catalytic materials contain hybrid inorganic/polymer carriers and preliminarily obtained molecular catalysts immobilised on them. Hybrid inorganic/polymer carrier consists of hybrid inorganic/polymer compound, in which organic polymers are chemically bound with at least one inorganic compound, selected from the group, consisting of silicic acid compound, tungstic acid compound, molybdic acid compound and stannic acid, and immobilised preliminarily obtained molecular catalyst contains at least one atom or ion of transition metal, selected from groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, VIII of periodic system of elements, which one or several ligand(s) is(are) bound with.
EFFECT: claimed catalytic material acts as heterogenic catalyst with selectivity, comparable with selectivity, observed in homogenous phase, with said catalyst being insoluble in reaction solvent and easily removable from reaction mixture.
27 cl, 3 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
INORGANIC/POLYMER CATALYST HYBRID MATERIALS WITH HIGH ACTIVITY IN DIFFERENT SOLVENTS | 2012 |
|
RU2584988C2 |
INORGANIC/POLYMER HYBRID CATALYTIC MATERIALS, WHICH CONTAIN METAL NANOPARTICLES | 2011 |
|
RU2574066C2 |
METHOD OF PREPARING RHODIUM-CONTAINING CATALYST | 0 |
|
SU1734816A1 |
METHOD OF ENANTIOSELECTIVE HYDRATION OF AMINOALCOHOLS | 2003 |
|
RU2340594C2 |
METHOD FOR ASYMMETRICAL HYDROGENATION OF ACRYLIC ACID DERIVATIVES, CATALYSED BY TRANSITION METALS, AND NOVEL CATALYST SYSTEM FOR ASYMMETRICAL CATALYSIS WITH TRANSITION METALS | 2005 |
|
RU2415127C2 |
METHOD OF OBTAINING ALDEHYDEES BY HYDROFORMATION WITH MODIFICATION OF LIGANDS BY ACETALIZATION | 2015 |
|
RU2628609C2 |
RHODIUM-CONTAINING HETEROGENEOUS CATALYSTS FOR PROCESSES OF PRODUCING PROPANAL AND DIETHYL KETONE BY HYDROFORMYLATION OF ETHYLENE | 2018 |
|
RU2711579C1 |
METHOD OF PRODUCING GLYCOL ALDEHYDE | 2004 |
|
RU2371429C2 |
IMMOBILIZED CATALYST FOR MONO-AND COPOLYMERIZATION OF OLEFINS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING HOMO-AND COPOLYMERS OF OLEFINS | 1999 |
|
RU2171814C1 |
COMPOSITION FOR CARBONYLATION CATALYST | 1993 |
|
RU2103064C1 |
Authors
Dates
2015-02-20—Published
2010-03-31—Filed