PREPARATION OF SUBSTITUTED 2-FLUOROACRYLIC ACID DERIVATIVES Russian patent published in 2015 - IPC C07C67/317 C07C69/653 

Abstract RU 2553990 C2

FIELD: chemistry.

SUBSTANCE: invention relates to an improved process for the preparation of compounds of formula . The process involves the conversion of the compound of formula into a compound of formula (I) in the presence of at least one base and in the presence of at least one polymerisation inhibitor, selected from 2,2,6,6-tetramethylpiperidine-N-oxyl, sulphur, p-benzoquinone, 4-tert-butylpyrocatechol, phenothiazine, di-tert-butylhydroxytoluene or mixtures of these polymerisation inhibitors. In the compounds of formulas (I) and (II) R1 and R2 are identical or different and, independently of one another, represent hydrogen, C1-C15-alkyl, C6-C24-aryl,or C1-C15-alkoxy, R3 is C1-C15-alkoxy, and X in formula (II) represents Cl, Br, I or pseudohalogen.

EFFECT: invention provides the process for the production of compounds with good yields and high purities.

14 cl, 4 ex

Similar patents RU2553990C2

Title Year Author Number
BENZOYLCYCLOHEXANEDIONES, HERBICIDE AGENT AND METHOD FOR CONTROL OF WEEDS BASED ON THEREOF 1999
  • Van Almzik Andreas
  • Vil'Ms Lotar
  • Auler Tomas
  • Biringer Khermann
  • Rozinger Kristofer
RU2237660C2
ANTHRANILIC ACID DIAMIDES, METHOD FOR CONTROL OF INSECTS, COMPOSITION FOR CONTROL OF INSECTS 2002
  • Klark Dehvid Alan
RU2299198C2
COMPOSITIONS FOR LOCAL APPLICATION, INCLUDING DERIVATIVE OF 1-N-ARYL-PYRASOL AND FORMAMIDINES 2004
  • Bekkh Al'Bert
  • Kramer Luis Gustavo
  • Soll Mark D.
RU2361401C2
AMIDES OF ANTHRANILIC ACID IN COMBINATION WITH FUNGICIDES 2011
  • Funke Kristian
  • Khungenberg Khajke
  • Fisher Rjudiger
RU2578801C2
HERBICIDAL COMPOSITION CAPABLE OF PRODUCING SYNERGISTIC EFFECT AND METHOD FOR COMBATTING UNDESIRED WEED VEGETATION IN USEFUL VEGETATIONAL CULTURES 1991
RU2041628C1
ORTHO-SUBSTITUTED ARYLAMIDES, METHOD FOR PEST CONTROLLING, COMPOSITION FOR PEST CONTROLLING, AND INTERMEDIATE 2002
  • Finkel'Stejn Brjus Lorens
  • Lehm Dzhordzh Filip
  • Selbi Tomas Pol
  • Stivenson Tomas Martin
RU2283839C2
4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES 2014
  • Ekkelbardzher Dzhozef D.
  • Epp Dzheffri B.
  • Fildz Stefen Krejg
  • Fisher Lindsi G.
  • Dzhampetro Natali K.
  • Gyuntenspberger Katerine A.
  • Lou Kristian T.
  • Petkus Dzheff
  • Rot Dzhoshua
  • Sachivi Norbert M.
  • Shmittser Pol Richard
  • Siddall Tomas L.
  • Van Nik Kh.
RU2672587C2
INSECTICIDE ANTHRANYLAMIDES 2001
  • Lehm Dzhordzh P.
  • Majers Brajan P.
  • Selbi Tomas P.
  • Stivenson Tomas M.
RU2278852C2
CYCLIC AMIDES OR AGRICULTURALLY ACCEPTABLE SALTS THEREOF, FUNGICIDAL COMPOSITION, METHOD OF CONTROLLING PLANT DISEASES INDUCED BY PHYTOPATHOGENIC FUNGI 1994
  • Braun Richard Dzhejms
  • San King-Mo
  • Frejz'Er Debora Ann
RU2126392C1
METHOD FOR PRODUCING AN INHIBITOR OF THE COAGULATION FACTOR XIA AND AN INTERMEDIATE THEREOF 2019
  • Si, Chzhosyun
  • Fen, Intsyan
  • Fen, Tszyun
  • Khe, Fen
  • Khuan, Tszyan
  • Mao, Yanli
  • Van, Yun
  • Gan, Chzhuntszyun
RU2779013C2

RU 2 553 990 C2

Authors

Kirkhkhoff Jan

Krajs Mikhaehl'

Dates

2015-06-20Published

2010-06-23Filed