FIELD: chemistry.
SUBSTANCE: claimed invention relates to method of obtaining polyarylates. Described is method of obtaining polyarylates by emulsion polycondensation, which includes preparation of organic-water-salt-alkali (THF-H2O-NaCl) solution of bis-phenol, cooling said solution to (10±4)°C, and introduction of melt of chloroanhydrite of aromatic dicarboxylic acid into it with intensive mixing, precipitation, washing and drying of target product, characterised by the fact that polyarylate-matrix is supplied at the stage of bis-phenol solution preparation simultaneously with bis-phenol in amount from 0.75 to 1.3 wt. p. per 1 wt. p. of bis-phenol, with neutralisation stage and precipitation being performed simultaneously by supply of acid (neutralising agent) and water (precipitating agent) into reaction medium.
EFFECT: obtaining high-molecular-weight polyarylate with improved exploitation characteristics.
3 cl, 2 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PRODUCTION OF POWDER AROMATIC COPOLYMERS | 2003 |
|
RU2248377C1 |
METHOD OF POLYARYLATES PRODUCTION | 0 |
|
SU729208A1 |
METHOD OF PREPARING AROMATIC POLYAMIDES | 0 |
|
SU789534A1 |
0 |
|
SU170668A1 | |
0 |
|
SU140990A1 | |
0 |
|
SU184447A1 | |
POLY(ARYLATE-SULFONES) FOR CONSTRUCTION MATERIALS AND METHOD OF OBTAINING SAME | 0 |
|
SU622823A1 |
METHOD OF OBTAINING POLYAMIDE ESTERS | 0 |
|
SU533142A1 |
0 |
|
SU203891A1 |
Authors
Dates
2015-07-20—Published
2013-07-29—Filed