FIELD: chemistry.
SUBSTANCE: invention relates to modified filler, including filler, which contains adsorbed on it triazole, which has the following formulae:
or ,
where Zb represents alkylene C1-C4-group, where b equals 0 or 1; X represents H, NH2, SH, NHNH2, CHO, COOR, COOH, CONR2, CN, CH3, OH, NDD' or CF3; Y represents H or NH2; A is functional group, which represents SkR, SSO3H, SO2NRR', SO2SR, SNRR', SNQ, SO2NQ, S-(1,4-pyperazinediyl)-SR, 2-(1,3-dithianyl) or 2-(1,3-dithiolanyl); where R and R', which are similar or different, represent hydrogen, branched or non-branched C1-C12-alkyl, alkenyl, alkinyl; aryl; heteroaryl; alkylaryl; arylalkyl; arylene; heteroarylene or alkylarylene; k equals integer number from 1 to 8, if R represents H, with k equal 2-8 in other cases; Q represents (CH2)w, (CH2)xO(CH2)z, (CH2)xNR(CH2)z or (CH2)xS(CH2)z, where x equals 1-6, z equals 1-6 and w equals 2-6; E represents group Sw, where w equals 2-8, SSO, SSO2, SOSO2, SO2SO2; and said triazole can be, but not obligatorily, N-substituted with NDD'-substituent, where D and D', which are similar or different, represent H or C1-C4alkyl. Invention also relates to modified filler, including filler, containing triazole, bound to it, to elastomer composition, which contains modified filler, and to industrial product.
EFFECT: increase of elastomer composition wear resistance, improvement of hysteresis in elastomer composition and increase of elastomer composition wear resistance and reduction of hysteresis.
13 cl, 35 tbl, 103 ex
Authors
Dates
2015-08-10—Published
2011-09-02—Filed