FIELD: chemistry.
SUBSTANCE: invention relates to highly molecular compounds, in particular to method of obtaining water-soluble polymers based on quaternary salts of dimethylaminoethylmethacrylate, which can be applied as flocculants, effective in purification of sewage water of different origin. Claimed is method of obtaining water-soluble polymers based on quaternary salts of dimethylaminoethylmethacrylate of general formula , where R1=-CH3, -CH2-CH3 or -CH2-C6H5; X-=Cl-, Br-, -OSO3CH3, average weight molecular weight of synthesised polyelectrolytes is higher than 106, with monomer being polymerised in water solution at 20°C, target product of polymerisation is extracted, purified by dialysis and dried lyophilically; method is characterised by the fact that sodium dodecylsulphate is additionally introduced into solution with molar ratio monomer:sodium dodecylsulphate equal 1-10:1, with radical initiator tret-buthylperoxypropanol-2 being applied as initiator, and monomer being polymerised in argon medium.
EFFECT: obtaining cation highly molecular polyelectrolyte, possessing reduced polydispersity.
6 ex, 1 tbl
Title | Year | Author | Number |
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METHOD OF PREPARING POLYMER COATING ON METAL SURFACE | 2008 |
|
RU2380173C1 |
POLY-N,N,N,N-TRIMETHYLMETHACRYLOYLOXYETHYLAMMONIUM BENZENE SULFONATE AS A FLOCCULANT | 1995 |
|
RU2109020C1 |
COMPOSITION HAVING FLOCCULATE ACTION WHICH COMPRISES POLY-N,N,N,N-TRIMETHYLMETACRYLOYLOXYETHYL AMMONIUM METHYL SULFATE AND METHOD FOR PRODUCTION OF COMPOSITION | 1993 |
|
RU2106370C1 |
METHOD FOR OBTAINING TEMPERATURE SENSITIVE POLYMERIC COATING ON METAL SURFACE | 2009 |
|
RU2405859C1 |
WATER-SOLUBLE COPOLYMERS COMPRISING NITROGEN ATOMS, COMPOSITIONS BASED ON WATER-SOLUBLE HOMOPOLYMERS AND COPOLYMERS COMPRISING NITROGEN ATOMS AND METHOD FOR PREPARING COMPOSITIONS OF WATER-SOLUBLE HOMOPOLYMERS AND COPOLYMERS | 2001 |
|
RU2223975C2 |
METHOD OF PRODUCING CATHIONIC (CO)POLYMERS | 0 |
|
SU1595849A1 |
METHOD OF PRODUCTION OF POLYMERIC COATING ON METAL SURFACE | 2008 |
|
RU2379123C1 |
METHOD OF PRODUCING WATER-SOLUBLE CATIONIC POLYELECTROLYTE | 2010 |
|
RU2450027C1 |
METHOD OF SYNTHESIS OF POLY-N,N,N,N-TRIMETHYLMETHACRYLOYLHYDROXYETHYL AMMONIUM METHYLSULFATE | 1994 |
|
RU2088593C1 |
PROCESS FOR PREPARING POLYELECTROLYTE | 0 |
|
SU954400A1 |
Authors
Dates
2015-08-20—Published
2014-10-16—Filed