FIELD: chemistry.
SUBSTANCE: reaction of equimolar amounts of bis(2-hydroxyphenyl)ester of oligoethylene glycol, dichloro-substituted oligoethylene glycol and sodium hydroxide is carried out in the presence of a catalyst - silicon oxide or a metal oxide (amphoteric or basic), preferably nano-sized, while stirring in dimethylformamide at 100-110°C, which can be used as selective extractants of metal cations, including radioactive metals.
EFFECT: high chemical selectivity of the reaction, which is expressed in the high output of desired compounds, short duration of the reaction and considerably easy implementation of the process.
11 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING BIS(2-HYDROXYPHENYL)ETHER OF OLIGOETHYLENE GLYCOL IN MONOHYDRATE FORM | 2014 |
|
RU2564257C1 |
METHOD OF TRIALKYLORTHOFORMATE SYNTHESIS | 1993 |
|
RU2072978C1 |
SUBSTITUTED DI-(FORMYLARYL)-POLYESTERS OR THEIR COORDINATION COMPOUNDS OR THEIR PHARMACEUTICALLY ACCEPTABLE ADDITIVE SALTS, METHOD OF THEIR SYNTHESIS AND PHARMACEUTICAL COMPOSITION ON SAID | 1998 |
|
RU2137750C1 |
METHOD OF PRODUCING 1,5-BIS(2-HYDROXYPHENOXY)-3-OXAPENTANE MONOHYDRATE | 2012 |
|
RU2483055C1 |
METHOD OF PRODUCING CINNAMIC ACIDS | 0 |
|
SU1597357A1 |
METHOD OF PREPARING 1,5-BIS(2-HYDROXYPHENOXY)-3-OXAPENTANE MONOHYDRATE | 2001 |
|
RU2203882C1 |
0 |
|
SU1781203A1 | |
-DI/CARBAMOYLAMINOXY/OLIGOOXAALKANES AS INTERMEDIATE PRODUCTS FOR OBTAINING DIALKOXYUREAS | 0 |
|
SU1836337A3 |
PROCESS FOR PREPARING 18-CROWN-6 | 1992 |
|
RU2044733C1 |
METHOD OF OBTAINING 4-AMINO-3-CHLORO-5-FLUORO-6-(SUBSTITUTED)PICOLINATES | 2012 |
|
RU2539578C1 |
Authors
Dates
2015-09-27—Published
2014-09-22—Filed