METHOD OF OBTAINING 4-AMINO-3-CHLORO-5-FLUORO-6-(SUBSTITUTED)PICOLINATES Russian patent published in 2015 - IPC C07D213/803 C07D213/04 A01N43/40 A01P13/00 

Abstract RU 2539578 C1

FIELD: chemistry.

SUBSTANCE: invention relates to method of obtaining 4-amino-3-chloro-5-fluoro-6-(substituted)picolinate of formula I , where R represents (C1-C4)alkyl, cyclopropyl, (C2-C4)alkenyl or phenyl, which contains from 1 to 4 substituents, as such independently selected are halogen, (C1-C4)alkyl, (C1-C4)haloalkyl, (C1-C4)alkoxy or (C1-C4)haloalkoxy; and R1 represents (C1-C12)alkyl or non-substituted (C7-C11)arylalkyl, which includes fluoride substitution, amination, reaction with hydrazine, halogenation, hydrolysis and etherification, as well as catalised by transition metals combination.

EFFECT: method improvement.

4 cl, 6 ex

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RU 2 539 578 C1

Authors

Chzhu Juan'Min

Uajteker Gregori T.

Arndt Kim Eh.

Renga Dzhejms M.

Frouehs Robert D.

Dates

2015-01-20Published

2012-01-24Filed