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2 565 782

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IPC

C07D211/10(2006-01-01)

(21) (22)

Application

2014118800/04, 2014-05-08

(24)

Start date

2014-05-08

(22)

Actual filing date

2014-05-08

(45)

Published

2015-10-20

(72)

Inventor

Dzhemilev Usein MemetovichTuktarov Ajrat RamilevichKhuzin Artur Al'BertovichShakirova Zul'Fija Rasimovna

(73)

Holder

Federal'Noe Gosudarstvennoe Bjudzhetnoe Uchrezhdenie Nauki Institut Neftekhimii I Kataliza Rossijskoj Akademii Nauk

METHOD OF OBTAINING 6-ALKYL(ARYL)-2,3-(C-I)[5,6]FULLERO-2,3,4,5-TETRAHYDROPYRIDINES Russian patent published in 2015 - IPC C07D211/10

Abstract RU 2565782 C1

FIELD: chemistry.

SUBSTANCE: invention relates to field of organic synthesis, namely to method of obtaining 6-alkyl(aryl)-2,3-(C₆₀-I_H)[5,6]fullero-2,3,4,5-tetrahydropyridines of general formula

where R=C₅H₁₁, Ph, 2-Naph; characterised by the fact that C₆₀-fullerene interacts with alkyl- or arylnitriles of formula RCN (R=C₅H₁₁, Ph, 2-Naph) in toluene under action of catalyst Ti(OiPr)₄ in presence of EtMgBr,with molar ratio C₆₀ : nitrile : Ti(OiPr)₄ : EtMgBr = 1:(5-15):(5-15):(30-50), at temperature 80°C for 5-30 min.

EFFECT: method of obtaining fulleroheterocycles, which can be applied as complexants, sorbents, biologically active compounds, as well as in creation of novel materials with specified electronic, magnetic and optic properties, has been elaborated.

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RU 2 565 782 C1

Authors

Dzhemilev Usein Memetovich

Tuktarov Ajrat Ramilevich

Khuzin Artur Al'Bertovich

Shakirova Zul'Fija Rasimovna

Dates

2015-10-20—Published

2014-05-08—Filed