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2 629 756

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IPC

C07C211/35(2006-01-01)

C07C209/66(2006-01-01)

C07C209/48(2006-01-01)

(21) (22)

Application

2016110948, 2016-03-24

(24)

Start date

2016-03-24

(22)

Actual filing date

2016-03-24

(45)

Published

2017-09-01

(72)

Inventor

Dzhemilev Usein MemetovichTuktarov Ajrat RamilevichShakirova Zulfiya Rasimovna

(73)

Holder

Federalnoe Gosudarstvennoe Byudzhetnoe Uchrezhdenie Nauki Institut Neftekhimii I Kataliza Ran

METHOD FOR PRODUCING 1'-[N-(ARYLMETHYL)AMINO]-(C60-IH)[5,6]FULLERO [2',3':1,9] CYCLOPROPANES Russian patent published in 2017 - IPC C07C211/35 C07C209/66 C07C209/48

Abstract RU 2629756 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a new method of producing new 1'-[N-(arylmethyl)amino]-(C₆₀-I_h)[5,6]fullero [2',3':1,9] cyclopropanes of general formula (1), which can be used as complexing agents, sorbents, biologically active compounds, and also of creating new materials with specified electronic, magnetic and optical properties. In general formula (1)

The method for producing compounds of general formula (1) is that C₆₀-fullerene reacts with isonitriles of the formula ArCH₂N⁺≡C- (where Ar = Ph, 2-ClPh, 2-thiophenyl, 2-furyl) in chlorobenzene under the action of the catalyst Ti (OiPr)₄in the presence of EtMgBr, taken in the molar ratio of C₆₀: isonitrile: Ti (OiPr)₄: EtMgBr = 1: (2-6):(1-5):(6-10), at a temperature of 100°C for 5-30 minutes. 1'-(N-(arylmethyl)amino]-(C₆₀-I_h)[5,6]fullero[2',3':1,9] cyclopropanes (1) in a yield of 20-55%.

EFFECT: increasing the yeild.

1 tbl, 10 ex

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RU 2 629 756 C1

Authors

Dzhemilev Usein Memetovich

Tuktarov Ajrat Ramilevich

Shakirova Zulfiya Rasimovna

Dates

2017-09-01—Published

2016-03-24—Filed