FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining silane-modified polyurethane binding agent (SPU-polymer), which contains terminal reactionable alkoxysilane groups, which can be applied as polymeric base in compositions of adhesives, sealants and coatings for different purpose, which are moisture-curable. Method consists in interaction of bifunctional polymer of formula (I) X-R-X, where R stands for residue of polyether chain, X stands for hydroxyl group, with organoalkoxysilane of formula (II) Y-R1-Si(R2)m(OR3)3-m, where Y stands for isocyanate group in presence of vinylalkoxysilane of formula (III) CH2=CH-Si(R4)n(OR5)3-n. In compounds (II) and (III) each of R1, R2, R3, R4, R5 has the same or different values and stands for hydrocarbon group, which contains from 1-12 carbon atoms, m, n = 0, 1 or 2.
EFFECT: method makes it possible to obtain SPU-polymer with lower viscosity, stable in storing and processing, without formation of additional internal cross-linking, duration of synthesis is reduced and stability of synthesis process results is ensured, cost of obtained product is reduced.
12 cl, 2 dwg, 2 tbl, 12 ex
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Authors
Dates
2015-11-10—Published
2014-11-20—Filed