FIELD: chemistry.
SUBSTANCE: method includes reaction of bifunctional polymer of formula (I) X-R-X, where R stands for ether chain residue, X stands for hydroxygroup, with respective diisocyanate of formula (II) X-R6-X, where X stands for isocyanate group, R6 stands for hydrocarbon group, which contains to 16 carbon atoms, and organoalkoxysilane of formula (III) Y-R1-Si(R2)m(OR3)3-m, where Y stands for primary or secondary aminogroup, in presence of vinylalkoxysilane of formula (IV) CH2=CH-Si(R4)n(OR5)3-n, and in compounds (III) and (IV) each of R1, R2, R3, R4, R5 has the same or different values and stands for hydrocarbon group, which contains 1-12 carbon atoms, m, n=0, 1 or 2.
EFFECT: method makes it possible to obtain polymer with low viscosity, stable in storing and processing, without requiring additional internal cross-linking, duration of synthesis is reduced from 12 hours to 5-6 hours, reproducibility is improved and stability of synthesis process results is ensured of synthesis process results, cost of obtained product is reduced due to reduction of synthesis time and reduction of its staging.
17 cl, 1 dwg, 3 tbl, 18 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR OBTAINING SILANE-MODIFIED POLYURETHANE BINDING AGENT | 2014 |
|
RU2567551C1 |
HIGHLY CONCENTRATED WATER NANO-SIZE PU-DISPERSION, WHICH DOES NOT CONTAIN SOLVENT, METHOD OF ITS OBTAINING AND APPLICATION | 2014 |
|
RU2554882C1 |
POLYMER COMPOSITION BASED ON MOISTURE-CURABLE URETHANE SILOXANE RUBBER | 2011 |
|
RU2475509C1 |
METHOD FOR OBTAINING POLYETHERURETHANETHIOLES WITH ALCOXYSILANE GROUPS | 2018 |
|
RU2669567C1 |
METHOD FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF ORGANOSILANES CONTAINING EPOXY FUNCTIONAL GROUPS, AS WELL AS CO-CONDENSATION THEREOF WITH OTHER ALKOXY SILANES WITH ORGANIC FUNCTIONAL GROUPS | 2008 |
|
RU2495059C2 |
REACTIVE HOT-MELT ADHESIVES WITH IMPROVED ADHESION | 2014 |
|
RU2698661C2 |
CURABLE POLYMER COMPOSITION | 2006 |
|
RU2466169C2 |
COATING | 2010 |
|
RU2529862C2 |
PREPOLYMER COMPOSITION FOR MAKING SEALANTS AND COATINGS, PREPARATION METHOD THEREOF AND SEALANT BASED ON SAID COMPOSITION (VERSIONS) | 2004 |
|
RU2434889C2 |
MOISTURE-CURABLE GLUE-MELT WITH HIGH ADHESION STRENGTH AND FAST SETTING TIME | 2016 |
|
RU2723880C2 |
Authors
Dates
2015-11-10—Published
2015-01-15—Filed