METHOD OF PRODUCING PARA-AMINOPHENOLS Russian patent published in 2015 - IPC C07C215/76 C07C213/00 B01J31/22 

Abstract RU 2567552 C1

FIELD: chemistry.

SUBSTANCE: method includes oxidising corresponding aromatic amines in an aqueous-organic solvent with singlet oxygen, generated by irradiation with visible light in the presence of substituted phthalocyanines as photosensitisers. Compounds of the following structural formula are preferably used as substituted phthalocyanines: , R=H, t-Bu, R1=H, PhSO2, t-Bu, R2=H, PhSO2, M=ZN, Al, in both homogeneous and heterogenised form. The light source can be a laser or LEDs. The phthalocyanines used are known compounds.

EFFECT: selective production of para-aminophenols in a single step with high output and can be used industrially.

3 cl, 1 tbl, 14 ex

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Authors

Kalija Oleg Leonidovich

Fedorova Tat'Jana Mikhajlovna

Kuznetsova Nadezhda Igorevna

Derkacheva Valentina Mikhajlovna

Luk'Janets Evgenij Antonovich

Kudrjavtseva Natalija Ivanovna

Dates

2015-11-10Published

2014-09-19Filed