SYMMETRICAL CROWN-CONTAINING DIENONES AS OPTICAL MOLECULAR SENSORS FOR DETECTING ALKALI, ALKALI-EARTH METAL AND AMMONIUM CATIONS AND METHOD FOR PRODUCTION THEREOF Russian patent published in 2015 - IPC C07D323/00 G01N21/64 

Abstract RU 2568614 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a new type of compounds - symmetrical crown-containing dienones of general formula I , where n=1, 2; m=0, 1, and a method for production thereof, which includes reacting cycloalkanones of general formula II , where n=1, 2, with formyl derivatives of benzo-crown-ethers of general formula III , where m=0, 1, and the process is carried out in a mixture of an organic solvent and water or in a medium of an organic solvent.

EFFECT: compounds of formula I and materials based thereon can be used in optical chemical sensors for colorimetric and luminescent determination of alkali, alkali-earth metal and ammonium cations, for example for determining trace elements of said ions in biological liquids, in industrial plants and effluents, for environmental monitoring.

3 cl, 2 dwg, 4 ex

Similar patents RU2568614C1

Title Year Author Number
BIS-AZA-18-CROWN-6-CONTAINING DIENONES AS OPTICAL MOLECULAR SENSORS FOR DETERMINING CATIONS OF ALKALI, ALKALI-EARTH METALS AND DIAMMONIUM AND A METHOD OF PRODUCING SAME 2018
  • Fomina Marina Viktorovna
  • Nuriev Vyacheslav Nazimovich
  • Zyuzkevich Filipp Sergeevich
  • Naumova Anastasiya Vitalevna
  • Kurchavov Nikolaj Anatolevich
  • Vatsadze Sergej Zurabovich
  • Gromov Sergej Pantelejmonovich
RU2689621C1
CHEMOSENSORY OPTICAL MATERIALS FOR DETECTING METAL CATIONS WITH LARGE IONIC RADIUS AND DIAMMONIUM IONS BASED ON CROWN-CONTAINING BIS-STYRYL DYES, IMMOBILISED IN POLYMER FILMS AND METHODS OF MAKING SAID MATERIALS 2008
  • Gromov Sergej Pantelejmonovich
  • Zajtsev Sergej Jur'Evich
  • Vedernikov Artem Igorevich
  • Ushakov Evgenij Nikolaevich
  • Lobova Natal'Ja Anatol'Evna
  • Kondratjuk Dmitrij Vladimirovich
  • Tsar'Kova Marina Sergeevna
  • Varlamova Elena Arkad'Evna
  • Bondarenko Viktor Viktorovich
  • Timonin Andrej Nikolaevich
  • Alfimov Mikhail Vladimirovich
RU2389745C2
BISCROWNCONTAINING DISTIRILBENZENES AS FLUORESCENT MOLECULAR SENSORS FOR DETECTING CATIONS OF ALKALI, ALKALI-EARTH METALS, AMMONIUM AND METHOD FOR PRODUCTION THEREOF 2015
  • Nuriev Vjacheslav Nazimovich
  • Fedorov Oleg Vladimirovich
  • Podjacheva Evgenija Sergeevna
  • Vedernikov Artem Igorevich
  • Kurchavov Nikolaj Anatolevich
  • Vatsadze Sergej Zurabovich
  • Gromova Tatjana Albertovna
  • Gromov Sergej Pantelejmonovich
RU2603135C1
CROWN-CONTAINING STYRYL DYES WITH AMMONIUM GROUP AT N-SUBSTITUTE OF HETEROCYCLIC RESIDUE AS PHOTO- AND THERMOSENSITIVE COMPOUNDS AND METHODS FOR THEIR PREPARING 2005
  • Gromov Sergej Pantelejmonovich
  • Vedernikov Artem Igorevich
  • Lobova Natal'Ja Anatol'Evna
  • Kuz'Mina Ljudmila Georgievna
  • Dmitrieva Svetlana Nikolaevna
  • Tikhonova Ol'Ga Vladimirovna
  • Alfimov Mikhail Vladimirovich
RU2278134C1
STYRYL DYES WITH AMMONIUM GROUP IN N-SUBSTITUTE OF HETEROCYCLIC RESIDUE AS PHOTOSENSITIVE COMPOUNDS AND METHOD OF MAKING SAID DYES 2008
  • Gromov Sergej Pantelejmonovich
  • Vedernikov Artem Igorevich
  • Sazonov Sergej Konstantinovich
  • Lobova Natal'Ja Anatol'Evna
  • Alfimov Mikhail Vladimirovich
RU2383571C1
BIS-N-METHYL AZA-CROWN-CONTAINING DIENONS AS OPTICAL MOLECULAR SENSORS FOR THE DETERMINATION OF CATIONS OF ALKALINE, ALKALINE EARTH METALS, AMMONIUM AND THE METHOD FOR THEIR PREPARATION 2021
  • Dmitrieva Svetlana Nikolaevna
  • Fomina Marina Viktorovna
  • Kurchavov Nikolaj Anatolevich
  • Gromov Sergej Pantelejmonovich
RU2781790C1
OPTICAL SENSOR MATERIALS FOR HEAVY AND TRANSIENT METALS BASED ON DITHIACROWN-CONTAINING BUTADIENYL DYES AND METHODS FOR THEIR PREPARING 2005
  • Gromov Sergej Pantelejmonovich
  • Zajtsev Sergej Jur'Evich
  • Vedernikov Artem Igorevich
  • Ushakov Evgenij Nikolaevich
  • Tsar'Kova Marina Sergeevna
  • Tul'Skaja Ekaterina Valer'Evna
  • Korshikova Anastasija Vladimirovna
  • Alfimov Mikhail Vladimirovich
RU2292368C1
ZINC DIMERIC COMPLEXES OF CROWN-CONTAINING STYRYL PHENANTHROLINES AS OPTICAL SENSORS ON CATIONS OF ALKALI-EARTH AND HEAVY METALS AND METHOD OF THEIR OBTAINING 2012
  • Kolosova Ol'Ga Jur'Evna
  • Gulakova Elena Nikolaevna
  • Shepel' Nikolaj Ehduardovich
  • Fedorov Jurij Viktorovich
  • Fedorova Ol'Ga Anatol'Evna
RU2516656C1
18(15) -CROWN-6(5)-CONTAINING STYRYL DYES AS SELECTIVE REAGENTS FOR AMMONIUM, ALKALI-AND ALKALI-EARTH METALS AND METHOD OF ITS PRODUCTION 1991
  • Gromov S.P.
  • Fedorova O.A.
  • Fomina M.V.
  • Alfimov M.V.
RU2012574C1
4-SUBSTITUTED N-ARYL-1,8-NAPHTHALIMIDES, EXHIBITING PROPERTIES OF FLUORESCENT SENSORS ON METAL CATIONS AND METHODS FOR PRODUCTION THEREOF 2012
  • Fedorova Ol'Ga Anatol'Evna
  • Fedorov Jurij Viktorovich
  • Panchenko Pavel Aleksandrovich
  • Sergeeva Antonina Nikolaevna
  • Oshchepkov Maksim Sergeevich
  • Oshchepkov Aleksandr Sergeevich
RU2515195C1

RU 2 568 614 C1

Authors

Nuriev Vjacheslav Nazimovich

Zjuz'Kevich Filipp Sergeevich

Vatsadze Sergej Zurabovich

Vedernikov Artem Igorevich

Gromov Sergej Pantelejmonovich

Dates

2015-11-20Published

2014-12-04Filed