FIELD: chemistry.
SUBSTANCE: invention relates to a method of recovering hydrocarbons from a polyolefin purge gas product. Method includes following steps: recovering a polyolefin product comprising one or more volatile hydrocarbons from a polymerisation reactor; contacting polyolefin product with a purge gas to remove at least a portion of volatile hydrocarbons to produce a polymer product having a reduced concentration of volatile hydrocarbons and a purge gas product enriched in volatile hydrocarbons, wherein volatile hydrocarbons comprise hydrogen, methane, one or more C2-12 hydrocarbons, or any combination thereof, and wherein purge gas product is at a pressure of about 50 kPa (abs) to about 250 kPa (abs); compressing purge gas product to a pressure of about 2,500 kPa (abs) to about 10,000 kPa (abs); cooling compressed purge gas product; separating cooled purge gas product into at least a first product, a second product, and a third product; and recycling at least a portion of at least one of first product as purge gas, second product to polymerisation reactor, or third product to purge gas product enriched in volatile hydrocarbons prior to compression. Invention also relates to a system.
EFFECT: use of present invention makes it possible to control pressure, which helps to protect potential polymerisation products at formation and increase potential for polymerisation.
21 cl, 4 tbl, 3 ex, 5 dwg
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Authors
Dates
2016-07-10—Published
2011-12-13—Filed