FIELD: chemistry.
SUBSTANCE: invention relates to use of one or more aminotriazine-based Mannich compounds of formula (I), and/or their dimers or trimers, and/or one or more of their preliminary condensate of formula (II) as antioxidants for organic materials. In formula (I) and (II)
,
A is O; R4 is R5-N-R6 group, connected to triazine ring with structure (I) or (II) by central nitrogen atom; R1, R2, R3, R5 and R6 represent hydrogen, or Q1 or group of formula (III) , R7 is hydrogen, where in case of A, equal to O, R7 is found once, R8 is selected independently from Q1 or can be group with structure (IV), where R8′ means R8 , n equals to 1 or 2, where n is in ortho-position to AR7, Q1 is selected from group comprising unsubstituted, linear or branched C1-C18-alkyl, unsubstituted, linear or branched C2-C12-alkenyl, unsubstituted C3-C7-cycloalkyl, unsubstituted C6-C10-aryl, m ranges from 2 to 20. Invention also relates to Mannich compound based on aminotriazine; methods of organic material stabilization against destruction; to polymer compositions; to use of polymer compositions.
EFFECT: technical result: Mannich compounds are obtained based on aminotriazine, which increase resistance of polymer to oxidative decomposition.
17 cl, 2 dwg, 5 tbl, 8 ex
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Authors
Dates
2016-08-10—Published
2012-09-20—Filed