FIELD: chemistry.
SUBSTANCE: invention relates to graft polymers based on polysaccharides and polypeptides. Graft polymer based on polysaccharides and polypeptides or respective derivatives thereof are obtained by free-radical polymerisation of A) a monomer selected from following, or a mixture of following monomers: (a) from 20 to 100 wt% acrylic acid or methacrylic acid, or mixture thereof, or salts thereof with an alkali metal, alkali-earth metal or ammonium, (b) from 0 to 80 wt% other monoethylenically unsaturated monomers, which can be copolymerised with monomer (a) and (c) from 0 to 5 wt% monomers containing per molecule at least 2 ethylenically unsaturated unconjugated double bonds in presence of B1) polysaccharides subjected to oxidative, hydrolytic or enzymatic decomposition, oxidised polysaccharides subjected to hydrolytic decomposition or subjected to enzymatic decomposition, or chemically modified decomposed products, chemically modified mono-, oligo-or polysaccharides, or mixtures of said compounds and B2) polypeptides subjected to hydrolytic or enzymatic decomposition and optionally chemically modified polypeptides, or mixtures of said compounds, with weight ratio A:(B1+B2) ranging from 60:40 to 1:99 and B1:B2 from 97:3 to 3:97. Also disclosed is a method of producing graft polymers, method of tanning leather, and tanned leather.
EFFECT: wider range of polymers for various types of tanning.
7 cl, 18 ex
Title | Year | Author | Number |
---|---|---|---|
GRANTED COPOLYMERS OF UNSATURATED MONOMERS AND SACCHARIDES AND PROCESS FOR PREPARATION THEREOF | 1993 |
|
RU2126020C1 |
BIODEGRADABLE COPOLYMERS, METHOD OF PREPARATION THEREOF, AND THEIR APPLICATION | 1994 |
|
RU2126019C1 |
PROCESS FOR TREATING TANNED LEATHER | 1989 |
|
RU2025490C1 |
METHOD OF LEATHER PRODUCTION | 2001 |
|
RU2182602C1 |
METHOD OF CONTROL OF POLYMER PARTICLES DISTRIBUTION ON SIZES IN PROCEEDING OF WATER POLYMER DISPERSION, WATER POLYMER DISPERSION AND ITS APPLICATION | 2013 |
|
RU2627365C2 |
MEANS FOR SOFTENING, DUBBING OR HYDROPHOBIC TREATING LEATHER AND FUR SKINS | 1992 |
|
RU2085593C1 |
LEATHER | 2008 |
|
RU2478120C2 |
AGENT FOR DECREASE OF LEATHER COMPONENT VOLATILITY | 1992 |
|
RU2078829C1 |
CLEANING COMPOSITIONS WITH AMPHIPHILIC GRAFT POLYMERS BASED ON POLYALKYLENE OXIDES AND VINYL ESTERS | 2007 |
|
RU2413756C2 |
COPOLYMERS FOR PREVENTION OF DEPOSITS IN WATER-BEARING SYSTEMS, THEIR PREPARING AND USING | 2003 |
|
RU2315060C2 |
Authors
Dates
2016-11-20—Published
2012-05-25—Filed