METHOD FOR HOLMIUM (III) SALT EXTRACTION FROM AQUEOUS SOLUTIONS Russian patent published in 2017 - IPC C22B59/00 C22B3/26 C01F17/00 

Abstract RU 2616748 C1

FIELD: chemistry.

SUBSTANCE: holmium (III) salts extraction method involves liquid extraction using isooctyl alcohol as an extractant. Solvate as holmium (III) dodecyl sulfate is conveyed through the aqueous to the organic phase. Anionic surfactant such as sodium dodecyl sulfate is applied in a concentration corresponding to the reaction stoichiometry: Ho+3+3C12H25OSO3Na=Ho[C12H25OSO3]3+3Na+, where Ho+3 - holmium cation, C12H25OSO3Na - is sodium dodecyl sulfate, Ho[C12H25OSO3]3 holmium (III) dodecyl sulfate solvate. Liquid extraction is carried out at pH 3.0-6.0, which allows to achieve 99% recovery of holmium (III) salts from aqueous solutions.

EFFECT: increased degree of holmium III salt extraction.

1 dwg, 1 ex

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RU 2 616 748 C1

Authors

Lobacheva Olga Leonidovna

Dzhevaga Natalya Vladimirovna

Dates

2017-04-18Published

2015-11-10Filed