FIELD: chemistry.
SUBSTANCE: invention relates to a process for producing a granular epoxidation catalyst ruggedized olefins, comprising mixing a powdery titanium silicalite with the binder component which is used as basic salt oxalate of aluminium in an amount of from 5 to 25 wt % based on the dry zeolite, shaping, drying and calcining granules. Before calcining the granules are dried to a moisture content of not more than 35%.
EFFECT: increasing the mechanical strength and the catalytic activity of titanium silicalite granular in epoxidation reactions of olefins.
4 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING GRANULAR TITANIUM-CONTAINING ZEOLITE | 2010 |
|
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|
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| METHOD OF FORMING TITANIUM SILICALITE | 2009 |
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| METHOD OF TITANIUM SILICALITE ENCAPSULATION IN POLYMERIC MATRIX | 2013 |
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RU2523547C1 |
| TITANIUM-CONTAINING ZEOLITE PRODUCTION METHOD | 2001 |
|
RU2256613C2 |
| OXIDATION CATALYST, METHOD OF PREPARATION THEREOF (VERSIONS), METHOD OF PREPARING OXIMES, METHOD OF HYDROXYLATION OF AROMATIC HYDROCARBONS, AND CATALYTIC WAY OF OXIDIZING HYDROCARBONS | 1993 |
|
RU2107545C1 |
| METHOD OF C-C-OLEFIN EPOXIDATION | 1996 |
|
RU2168504C2 |
