FIELD: chemistry.
SUBSTANCE: rubber material is described, provided with a barrier material in the form of a copolymer, and a tire including a rubber material. The copolymer is produced by metathesis polymerization with a ring opening a) of, at least, one first olefin monomer selected from the group consisting of cyclic olefin monomers with, at least, one endocyclic double carbon-carbon bond, in the alpha position to which there is no tertiary carbon atom substituted by A hydrogen atom, and b) of, at least, one second olefin monomer selected from the group consisting of cyclic olefin monomers with one endocyclic carbon-carbon double bond. In, at least, one alpha position, a tertiary carbon atom substituted by a hydrogen atom is present to the double bond. The copolymer is, at least, partially oxidized and the copolymer is produced without using polycyclic olefin monomers with, at least, two carbon-carbon double bonds or the amount of such monomers is less than 1 mol % in terms of the sum of the monomers.
EFFECT: proposal of alternative barrier materials for rubber products, in particular pneumatic tires, characterized by the possibility of simple, economical and effective use or possessing optimal or improved gas barrier properties.
19 cl, 4 tbl, 3 ex
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Authors
Dates
2017-10-06—Published
2013-08-02—Filed