FIELD: chemistry.
SUBSTANCE: catalyst is described comprising, wt %: [Ni(H2O)2]2[Mo4O11(C6H5O7)2] 29.0-36.0%; boron in the form of surface compounds - 0.4-1.6%; carrier - the rest; wherein the carrier comprises, wt %: aluminium borate Al3BO6 with the structure of norbergite - 5.0-25.0; sodium - no more than 0.03; γ-Al2O3 - the rest. Aluminium borate Al3BO6 with norbergite structure, is the particles with dimensions from 10 to 200 nm, characterized by interplanar distances of 3.2 and 2.8 A, with an angle of 53.8°between them. Boron in the form of surface compounds is characterized by absorption bands of 930-1040, 1230, 1385-1450 and 3695 cm-1 in IR spectra. After sulphidizing, the catalyst contains, wt %: Mo - 10.0-14.0; Ni - 3.0-4.3; S, 6.7-9.4; boron in the form of surface compounds - 0.5-2.0; carrier - the rest; wherein the carrier comprises, wt %: aluminium borate Al3BO6 with the structure of norbergite - 5.0-25.0; sodium - no more than 0.03; γ-Al2O3 - the rest.
EFFECT: maximum activity in desulfurization and denitrogenation during hydroprocessing of oil fractions with the boiling point above 360 degrees, with production of high-quality hydrocracking raw material.
5 cl, 7 ex, 2 tbl
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Authors
Dates
2018-02-13—Published
2017-09-25—Filed