FIELD: chemistry.
SUBSTANCE: invention relates to the method for obtaining oligogalogenphosphazenes and polyhalogenphosphazenes. A method for obtainingh oligo- and polyhalogenphosphazenes of the general formula [X(PX2=N)n-PX3]+A is proposed, where n=1÷5000, , or X-, X = Cl, Br. The method allows to receive targeted connections in one stage of the interaction of crystalline halogenosphorane of the general formula RX5 (more often RCl5) and silazane, in particular, a widely available hexamethyldisilazane, in the environment of chlorohydrocarbon.
EFFECT: method for obtaining the oligo- and polyhalogenphosphazenes with controlled molecular weight in one stage, from available reagents, which do not require a complicated loading order of the components and characterized by a small amount of the solvent used.
5 cl, 9 ex
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Authors
Dates
2018-02-27—Published
2017-05-25—Filed