METHOD FOR OBTAINING OLIHALOGENPHOSPHAZENES AND POLYHALOGENPHOSPHAZENES WITH REGULATED MOLECULAR MASS BY INTERACTION OF HALOGENOSPHORANES WITH HEXALCILDYSILAZANES Russian patent published in 2018 - IPC C08G79/02 C01B21/97 

Abstract RU 2645682 C1

FIELD: chemistry.

SUBSTANCE: invention relates to the method for obtaining oligogalogenphosphazenes and polyhalogenphosphazenes. A method for obtainingh oligo- and polyhalogenphosphazenes of the general formula [X(PX2=N)n-PX3]+A is proposed, where n=1÷5000, , or X-, X = Cl, Br. The method allows to receive targeted connections in one stage of the interaction of crystalline halogenosphorane of the general formula RX5 (more often RCl5) and silazane, in particular, a widely available hexamethyldisilazane, in the environment of chlorohydrocarbon.

EFFECT: method for obtaining the oligo- and polyhalogenphosphazenes with controlled molecular weight in one stage, from available reagents, which do not require a complicated loading order of the components and characterized by a small amount of the solvent used.

5 cl, 9 ex

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RU 2 645 682 C1

Authors

Gorlov Mikhail Vladimirovich

Bredov Nikolaj Sergeevich

Esin Andrej Sergeevich

Kireev Vyacheslav Vasilevich

Dates

2018-02-27Published

2017-05-25Filed