FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing cyclic halophosphazenes. Cyclic halophosphazenes of general formula (PX2= N)n, where n = 3÷16, X = Cl or Br, are obtained by reacting oligomeric halophosphazaphosphonium salts of general formula [X(PX2= N)n-1-PY3]+A or [PX3=N-PY3]+A, where A=PY6- or Cl-, and X and Y=Cl, Br and hexaalkyldisilazane HN (SiR3)2 in an inert solvent.
EFFECT: method is characterized by low amount of used solvent and possibility of performing synthesis at room temperature.
5 cl, 3 tbl, 8 ex
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Authors
Dates
2020-08-07—Published
2018-07-24—Filed