FIELD: chemistry.
SUBSTANCE: method for reduction of hexavalent chromium in oxide solid materials involves mixing of an oxide solid material containing Cr(VI) with a carbon-containing compound. The resulting mixture is then treated in a protective gas atmosphere in an indirectly heated reactor at a temperature of 700 to 1100°C and the reaction product is cooled in a protective gas atmosphere to at least 300°C. As the carbon-containing compound, a liquid compound is used in a temperature range of from 20 to 100°C.
EFFECT: invention allows to dispose the remnants of chromite ore by converting the hexavalent chromium, which is difficult to access and insoluble in water, to trivalent chromium.
32 cl, 2 tbl, 6 ex
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RU2555853C1 |
Authors
Dates
2018-03-01—Published
2013-07-05—Filed