FIELD: soil or rock drilling; mining.
SUBSTANCE: present invention relates to a method for treating subterranean oil-bearing formations comprising carbonate rocks in which the process includes at least the following steps: injecting an aqueous composition comprising at least one cationic surfactant (S) into at least a portion of the oil-bearing formation, allowing the composition to interact with oil-wet surfaces in the formation, wherein the cationic surfactant (S) has general formula (I) [R1-N(R2)(R3)(R4)]+ 1/mXm- (I), and R1, R2, R3, R4 and Xm- have the following values: R1: a group selected from the group of R1a and R1b, in which R1a is an aliphatic linear or branched hydrocarbon radical containing from 10 to 22 carbon atoms, and R1b is an aliphatic linear or branched hydrocarbon radical containing from 10 to 22 carbon atoms substituted with 1 to 3 OH groups, and R2, R3 and R4 can be the same or different and are selected from the group of R2a, R3a, R4a: alkyl groups containing from 1 to 4 carbon atoms,R2b, R3b, R4b: OH- substituted alkyl groups containing from 1 to 4 carbon atoms, and R2c, R3c, R4c: alkyl ether groups of formula -CH2CH2OCH2CH2OH and -CH2CH2OCH2CH2OCH2CH2OH, and Xm- is an anion in which m is 1, 2 or 3,provided that at least one of the groups R1, R2, R3 and R4 contains an OH group and the total number of OH groups in the surfactant (S) is from 1 to 4. Invention is developed in dependent claims of the invention.
EFFECT: technical result is an increase in the efficiency of treatment of subterranean formations.
16 cl, 3 tbl
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Authors
Dates
2018-06-22—Published
2014-01-24—Filed