FIELD: technological processes.
SUBSTANCE: invention relates to methods of producing a catalyst for polymerisation of butadiene and can be used in production of rubber of general purpose in the industry of synthetic rubber. Disclosed is a method of producing a catalyst for polymerisation of butadiene by reacting rare earth elements (REE) chlorides with a monohydric alcohol and a solvent, followed by mixing with a conjugated diene and an organoaluminium compound, method consists in that monoatomic alcohol is 2-ethylhexyl alcohol in molar ratio of rare-earth elements : 2-ethylhexyl alcohol = 1:1.8–3.0.
EFFECT: disclosed synthesis method enables to obtain a catalyst with high activity (yield of polybutadiene – 93–97 %) while reducing synthesis time thereof and obtaining a polymer with optimum Mooney viscosity.
1 cl, 6 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD FOR OBTAINING A CATALYST FOR ISOPRENE POLYMERIZATION | 2018 | 
									
  | 
                RU2684280C1 | 
| METHOD OF PRODUCING CATALYST FOR COPOLYMERISATION OF BUTADIENE WITH ISOPRENE | 2018 | 
									
  | 
                RU2684279C1 | 
| METHOD FOR OBTAINING A CATALYST FOR ISOPRENE POLYMERIZATION | 2017 | 
									
  | 
                RU2660414C1 | 
| METHOD OF PRODUCING POLYMERS AND COPOLYMERS OF CONJUGATED DIENES (VERSIONS) | 2009 | 
									
  | 
                RU2422468C1 | 
| METHOD OF PRODUCING ALCOHOL SOLVATES OF CHLORIDES OF RARE-EARTH ELEMENTS | 2008 | 
									
  | 
                RU2438981C2 | 
| METHOD FOR PREPARING CATALYST FOR POLYMERIZATION OF BUTADIENE AND COPOLYMERIZATION OF BUTADIENE WITH COUPLED DIENES | 2003 | 
									
  | 
                RU2267497C2 | 
| METHOD OF PRODUCTION OF POLYMERIZATION AND COPOLYMERIZATION CATALYST OF UNSATURATED HYDROCARBONS | 1998 | 
									
  | 
                RU2141382C1 | 
| METHOD OF OBTAINING CATALYST OF BUTADIENE POLYMERISATION AND CO-POLYMERISATION OF BUTADIENE WITH ISOPRENE | 2007 | 
									
  | 
                RU2345092C1 | 
| METHOD OF PROCUCING MODIFIED CIS-1,4(CO) | 2010 | 
									
  | 
                RU2426747C1 | 
| METHOD OF PREPARATION OF CIS-1,4-POLYBUTADIENE AND CIS-1,4- BUTADIENE-ISOPRENE COPOLYMER | 1994 | 
									
  | 
                RU2087488C1 | 
Authors
Dates
2019-04-05—Published
2018-06-26—Filed