FIELD: chemistry of high-molecular weight compounds, more particularly petrochemical industry. SUBSTANCE: present invention describes method of preparation of CIS-1,4-polybutadiene and butadiene-isoprene copolymer in hydrocarbon solvent in the presence of catalyst obtained by reaction of carboxylate compounds of rare-earth metal compound with halogen-containing organoaluminium compound in the presence of conjugated diene. The organoaluminium compound includes mixtures of dialkyl aluminium hydride, trialkyl aluminium and tetraalkyl dialumoxane. The claimed method makes it possible to increase substantially catalyst activity. EFFECT: more efficient preparation method. 2 cl, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
PROCESS FOR PREPARING CIS-1,4-POLYBUTADIENE AND CIS-1,4- BUTADIENE-ISOPRENE COPOLYMER | 1997 |
|
RU2127280C1 |
PROCESS FOR PREPARING CIS-1,4-POLYBUTADIENE AND CIS-1,4- COPOLYMER AND ISOPRENE | 1997 |
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RU2127281C1 |
METHOD OF SYNTHESIS OF CIS-1,4-POLYBUTADIENE | 1996 |
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RU2109759C1 |
METHOD OF PREPARATION OF CIS-1,4,POLYBUTADIENE | 1995 |
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METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1998 |
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RU2139298C1 |
METHOD FOR PRODUCTION OF 1,4-CIS-POLYBUTADIENE | 1995 |
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RU2099357C1 |
METHOD OF PREPARATION CIS-1,4-POLYBUTADIENE | 1998 |
|
RU2151777C1 |
METHOD OF PREPARATION OF OIL-FILLED 1,4-CIS-POLYBUTADIENE | 1994 |
|
RU2091399C1 |
METHOD FOR PRODUCTION OF CIS-1,4-DIENE RUBBER | 1995 |
|
RU2099359C1 |
METHOD FOR PRODUCTION OF BUTADIENE RUBBERS | 1997 |
|
RU2196781C2 |
Authors
Dates
1997-08-20—Published
1994-03-16—Filed