FIELD: chemistry.
SUBSTANCE: invention relates to versions of an environmentally safe hot-melt adhesive from renewable raw materials, as well as to an article using said glue and a method of producing said article. In one version, the hot-melt adhesive contains (a) a polyester resin; (b) a functionalised polyolefin or functionalised wax, (c) a tackifier and (d) a non-functionalised polyolefin having a homopolymer of monomer C2-C20 or copolymer C2-C20. This hot-melt adhesive as a polyester resin contains a homopolymer or copolymer of lactic acid, butylene succinate, hydroxybutyric acid or their mixture. In another version, the hot-melt adhesive contains from about 5–80 wt. % polylactic acid, from about 0.1–25.0 wt. % functionalised polyolefin or functionalised wax, a tackifier and up to about 50 wt. % polyolefin containing C2-C20-Monomers. Viscosity of said adhesive is less than 30 % after aging of adhesive for at least 72 hours at 320 °F (160 °C). Glue practically does not contain rubber elastomer. Produced article comprises a substrate and a hot-melt adhesive composition. Article represents a box, a cardboard box, a tray, a label, a book binding, a bag or a disposable article. Article is obtained by applying the adhesive onto the substrate, by applying the second substrate onto the applied adhesive.
EFFECT: invention enables to obtain hot-melt adhesives which have the same operational characteristics as conventional hot-melt adhesives made from oil-based starting materials.
9 cl, 4 tbl
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Authors
Dates
2019-09-03—Published
2015-09-04—Filed