METHOD OF PRODUCING ACRYLIC ACID FROM LACTIC ACID OR LACTIDE USING MOLTEN SALT CATALYSTS Russian patent published in 2020 - IPC C07C51/353 C07C51/363 C07C51/377 C07C53/19 C07C57/04 

Abstract RU 2714490 C1

FIELD: technological processes.

SUBSTANCE: invention relates to an improved method of producing acrylic acid with high selectivity and output, involving the following steps: a) contacting a stream of incoming materials containing lactic acid, lactide or mixtures thereof with a first molten salt catalyst in a first reactor at a first reaction temperature during a first reaction time to obtain a first stream containing 2-bromopropionic acid (2-BrPA); b) contacting said 2-BrPA with a second molten salt catalyst in a second reactor at a second reaction temperature for a second reaction time to obtain a second stream containing 3-bromopropionic acid (3-BrPA) and said acrylic acid; and c) contacting said 3-BrPA with an amine in a third reactor at a third reaction temperature for a third reaction time to obtain a third stream containing said acrylic acid; wherein said first molten salt catalyst comprises an anion (Br-) bromide; and wherein said second molten salt catalyst comprises Br-, wherein said acrylic acid of said second stream is combined with said acrylic acid of said third stream into production stream of said acrylic acid; wherein said acrylic acid in said production stream has a common yield of acrylic acid and total acrylic acid selectivity.

EFFECT: disclosed is an improved method of producing acrylic acid.

15 cl, 2 dwg, 6 tbl, 56 ex

Similar patents RU2714490C1

Title Year Author Number
METHODS OF PRODUCING ACRYLIC ACID FROM LACTIC ACID OR DERIVATIVES THEREOF IN LIQUID PHASE 2017
  • Albert, Jakob
  • Wasserscheid, Peter
  • Taccardi, Nicola
  • Nagengast, Jens
  • Kehrer, Matthias
  • Kadar, Julian
  • Collias, Dimitris, Ioannis
RU2711993C1
CATALYSTS FOR PRODUCING ACRYLIC ACID FROM LACTIC ACID OR DERIVATIVES THEREOF IN LIQUID PHASE 2017
  • Albert, Jakob
  • Wasserscheid, Peter
  • Taccardi, Nicola
  • Nagengast, Jens
  • Kehrer, Matthias
  • Kadar, Julian
  • Collias, Dimitris, Ioannis
RU2715707C1
CATALYSTS FOR CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Godlewski Jane Ellen
  • Collias Dimitris Ioannis
  • Wireko Fred C.
  • Mamak Marc Andrew
  • Redman-Furey Nancy Lee
RU2591192C2
CATALYTIC CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID AND DERIVATIVES THEREOF 2013
  • Lingoes Janette Villalobos
  • Velasquez Juan Esteban
  • Godlewski Jane Ellen
  • Collias Dimitris Ioannis
RU2586327C2
CATALYTIC CONVERSION OF LACTIC ACID INTO ACRYLIC ACID 2013
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
RU2598380C2
ARTIFICIAL CELLULOSE FIBRE AND NONWOVEN PRODUCT OR MATERIAL CONTAINING CELLULOSE FIBRE 2017
  • Kuehn, Joerg
  • Bernt, Ingo
  • Roggenstein, Walter
  • Seger, Bernd
RU2732131C1
DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCTION OF POLYETHERPOLYOLS 2000
  • Oms Piter
  • Khofman Jorg
  • Gupta Pramond
RU2248241C2
CATALYSTS FOR PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Godlewski Jane Ellen
  • Mamak Marc Andrew
RU2586329C2
PROCESS FOR PREPARATION OF ESTERS OF 2-ACETOXYALKANOIC ACIDS USING 3,6-DIALKYL-1,4-DIOXANE-2,5-DIONE OR POLY(ALPHA-HYDROXYALKANOIC ACID) AS A STARTING MATERIAL 2015
  • Kulshrestha, Aman
  • Schroeder, Joseph, David
RU2654480C2
METHOD OF PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Godlewski Jane Ellen
RU2587494C2

RU 2 714 490 C1

Authors

Albert, Yakob

Vassershid, Piter

Takkardi, Nikola

Nagengast, Jens

Kekher, Matias

Kadar, Yulian

Kollias, Dimitris, Ioannis

Dates

2020-02-18Published

2018-03-07Filed