FIELD: chemistry.
SUBSTANCE: invention relates to a molten salt catalyst for producing acrylic acid, acrylic acid derivatives or mixtures thereof, comprising an ionic liquid (IL) and an acid; wherein said IL has a phosphonium cation and a bromide anion (Br-); wherein said acid is soluble in said IL and selected from a group consisting of a Lewis acid, Bronsted acid and mixtures thereof; wherein said Lewis acid is selected from a group consisting of CaBr2, MgBr2, AlBr3, CuBr2 and mixtures thereof; and wherein said Bronsted acid has pKa less than 5 in water at 25 °C.
EFFECT: high output of acrylic acid, acrylic acid derivatives or mixtures thereof.
14 cl, 3 tbl, 140 ex
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Authors
Dates
2020-03-03—Published
2017-07-27—Filed