HIGHLY ACTIVE TRIMETALLIC MATERIALS USING COMPOUNDS OF SHORT-CHAIN QUATERNARY ALKYLAMMONIUM Russian patent published in 2021 - IPC C01G49/02 C01G51/04 C01G53/04 C01G37/02 C01G39/02 C01G41/02 B01J23/85 B01J27/47 B01J37/03 C10G45/08 C10G45/50 C10G45/60 B01J37/20 C10G47/04 

Abstract RU 2757250 C1

FIELD: chemistry.

SUBSTANCE: developed is a highly active trimetallic material containing mixed transition metal oxide and a method for production thereof. The material can be subjected to sulphidation producing metal sulphides used as a catalyst in a method for conversion, e.g., in hydrotreatment. Hydrotreatment can include hydrodenitrification, hydrodesulphurisation, hydrodemetallisation, hydrodesilication, hydrodearomatisation, hydroisomerisation, hydrorefining, hydrogenation purification, and hydrocracking. The material for preparing the catalyst comprises a mixed transition metal oxide with the formula: (MIa)m(MIIb)n(MIIIc)oOeq, wherein MI constitutes a metal or a mixture of metals selected from group VIII (group 8, 9 and 10 according to IUPAC); MII constitutes a metal selected from group VIB (group 6 according to IUPAC); MIII constitutes a metal selected from group VIB (group 6 according to IUPAC), different from MII; a, b, c, and e constitute the valence state of MI, MII, MIII and O; m, n, o, and q constitute the molar ratio of MI, MII, MIII, and O, wherein m/(n + o) equals 1/10 to 10/1, wherein n/o > 0 and 0 ≤ o/n ≤ 100, wherein q is greater than 0; and wherein a, b, c, e, m, n, o, and q satisfy the equation: a × m + b × n + c × o + e × q = 0, wherein the mixed transition metal oxide is characterised by an X-ray diffraction pattern containing the peaks visualised in Table A: Table A, 2θ (°) - d (Å) - 100 (I/Io); 8 to 14 - 6.320 to 11.043 - very weak; 34.5 to 36.5 - 2.460 to 2.598 - very strong; 53 to 55 - 1.668 to 1.726 - strong to very strong; 55 to 58 - 1.589 to 1.668 - weak to average; 58.5 to 62.5 - 1.485 to 1.576 - very weak; 62.8 to 63.8 - 1.458 to 1.478 - average; wherein the peak between the values of 2 θ(°) at 55 to 58 has a full width at the level of half of the maximum of more than 3°.

EFFECT: high activity of the hydrotreatment catalyst.

23 cl, 2 dwg, 1 tbl, 4 ex

Similar patents RU2757250C1

Title Year Author Number
POLYMETALLIC MATERIALS USING ALKYLAMMONIUM QUATERNARY COMPOUNDS 2018
  • Osman, Zara
  • Pan, Wei
RU2757484C1
HIGHLY ACTIVE QUATERNARY METAL MATERIALS USING SHORT-CHAIN QUATERNARY ALKYLAMMONIUM HALIDE COMPOUNDS 2018
  • Osman, Zara
  • Pan, Wei
RU2757982C1
HIGHLY ACTIVE QUATERNARY METAL MATERIALS USING SHORT-CHAIN QUATERNARY ALKYL AMMONIUM COMPOUNDS 2018
  • Osman, Zara
  • Pan, Wei
RU2746318C1
HIGHLY ACTIVE TRIMETALLIC MATERIALS USING SHORT-CIRCUIT QUATERNARY ALKYLAMMONIUM COMPOUNDS 2018
  • Pan, Wei
  • Koster, Susan C.
  • Osman, Zara
RU2744338C1
HIGHLY ACTIVE MATERIAL CONSTITUTING A MIXED OXIDE OF TRANSITION METALS, HIGHLY ACTIVE QUATERNARY METAL MATERIALS USING COMPOUNDS OF SHORT-CHAIN QUATERNARY ALKYL AMMONIUM 2018
  • Osman, Zara
  • Pan, Wei
RU2757295C1
MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM AND PREPARATION PROCESS 2012
  • Karati Andzhela
  • Galyardi Mariya Federika
  • Ferrari Marko Massimo
  • Zanardi Stefano
  • Marella Marchello
  • Tomazelli Mikele
RU2599255C2
TRANSITION METAL CRYSTALLINE OXYHYDROXIDE-MOLYBDATE 2016
  • Miller, Stuart
  • Koster, Susan, C.
RU2699794C1
DEHYDROGENATION CATALYST COMPOSITION 2020
  • Do, Phuong T.M.
  • Serban, Manuela
  • Sachtler, J.W. Adriaan
  • Cole, Matthew C.
  • Mowat, John P.S.
RU2809169C2
METHOD OF PRODUCING COMPOUND METAL-PHOSPHATE PRODUCT (VERSIONS) 2014
  • Markin Gennadij Khrisanfovich
  • Krupnov Vitalij Nikolaevich
  • Jurtaeva Elena Aleksandrovna
RU2579378C2
CATALYSTS FOR PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Godlewski Jane Ellen
  • Mamak Marc Andrew
RU2586329C2

RU 2 757 250 C1

Authors

Osman, Zara

Pan, Wei

Moscoso, Jamie G.

Dates

2021-10-12Published

2018-12-18Filed