METHOD FOR PRODUCING OLIGO-2,2-BIS(AZIDOMETHYL)OXIRANS Russian patent published in 2021 - IPC C07C247/04 C08G65/325 C08G65/08 

Abstract RU 2757594 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method for producing oligo-2,2-bis(azidomethyl)oxiranes of the formula H-[OCH2(CH2N3)2C-]n-O-R-[OCH2(CH2N3)2C-]nOH (II), where n=2, 4÷10, R=CH2CH2OCH2CH2, which consists in the azidation of oligo-2,2-bis(chloromethyl)oxiranes of the formula H-[OCH2(CH2Cl)2C-]n-O-R-[OCH2(CH2Cl)2C-|nOH (I), where n=2, 4÷10, R=CH2CH2OCH2CH2, using tetrabutylammonium chloride as a catalyst for interphase transfer, followed by precipitation of the reaction mixture into water, extraction of the target product with methylene chloride and its further distillation.

EFFECT: method for producing oligo-2,2-bis(azidomethyl)oxiranes of the formula (II) is developed, which can be used as plasticizers, binders to create highly effective compositions with an increased value of energy characteristics.

1 cl, 1 ex

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RU 2 757 594 C1

Authors

Shaekhov Timur Rashitovich

Sedacheva Mariia Aleksandrovna

Gatina Roza Fatykhovna

Mikhailov Iurii Mikhailovich

Dates

2021-10-19Published

2021-01-12Filed