METHOD FOR ALCOHOLYSIS OF BIOMASS FOR A PETROLEUM-BASED PLASTIC POLYFORMALDEHYDE MATERIAL Russian patent published in 2022 - IPC C08J11/24 C07D317/12 C07D319/06 C07D321/06 

Abstract RU 2770837 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method for decomposing a petroleum-based plastic polyformaldehyde material (POM) using a biomass. The proposed method includes the stages of: uniformly mixing alcohol produced from the biomass, polyformaldehyde and a catalyst in a solvent and sealing the mixture; wherein the catalyst is selected from H2SO4, Cu(OTf)2, In(OTf)3, Zn(OTf)2, Co(OTf)3, Ni(OTf)3, Cd(OTf)2, Tl(OTf)3, Cr(OTf)3, Fe(OTf)3, Zr(OTf)4, K(OTf), Li(OTf), Ca(OTf)2, Mg(OTf)2, Nd(OTf)3, Ce(OTf)3, Y(OTf)3, Yb(OTf)3, La(OTf)3, Er(OTf)3, and the solvent is selected from methanol, butanol, isopropanol, tert-butanol, acetone, ethyl acetate, cyclohexane, isooctane, dichloromethane, dichloroethane, chloroform, carbon tetrachloride and DMSO (dimethyl sulfoxide), and mixing and heating the sealed mixture to 40°C to 100°C to execute the reaction for 2 to 8 hours, cooling the reaction product to room temperature naturally, and isolating the product.

EFFECT: effective method for decomposing petroleum-based POM.

6 cl, 4 tbl

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RU 2 770 837 C1

Authors

Jin Xin

Yan Wenjuan

Yang Guang

Wang Mengyu

Li Yushan

Ma Shengyan

Zhang Guangyu

Liu Mengyuan

Jin Youhai

Yang Chaohe

Dates

2022-04-22Published

2021-03-05Filed