FIELD: oil and gas condensate purification.
SUBSTANCE: invention relates to methods for the oxidation-catalytic purification of oil and gas condensate from hydrogen sulfide and light mercaptans, in particular to the production of ready-to-use catalyst compositions for technologies for the purification of hydrocarbon feedstock from sulfur compounds used in the gas and oil industry. The catalytic composition contains 20-30 wt.% aqueous ammonia solution and a catalytic additive in the form of derivatives of cobalt phthalocyanine complexes. Derivatives of cobalt phthalocyanine complexes contain 0.05-5 wt.% halogen-substituted derivatives of cobalt phthalocyanine complexes of the general formula: [CoPC]Xn(SO3)22–2Cat+, where CoPC is a compound of the structural formula:
where R = R1= H+, with n=1 or 3: X = Cl, Br; Cat+ = H+, Na+, K+, NH4+; at n=2: X = Cl, Br; Cat+ = Na+, K+, NH4+.
EFFECT: stable liquid composition for efficient cleaning in one stage of hydrocarbon feedstock with a high content of hydrogen sulfide of 500-600 ppm and light mercaptans with a content of up to 460 ppm, prepared directly from the manufacturer, as well as high activity of the composition due to the use of halogen-substituted cobalt phthalocyanine derivatives in the composition.
1 cl, 1 tbl, 11 ex
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Authors
Dates
2022-06-21—Published
2021-09-20—Filed