FIELD: diesel fuel composition.
SUBSTANCE: proposed fuel composition based on diesel fraction, boiling in the range of 180-360°C, containing organic peroxides from the group of peroxyketals of general formula (1) as ignition promoters, where R1 and R2 are 2-phenylisopropyl or tert-butyl radical, R3 = R 4 is a methyl radical; selected from the following group: 2,2-di(2-phenylisopropylperoxy)propane, 2,2-di(t-butylperoxy)propane; or a mixture of cyclic derivatives obtained from two and three ketone molecules - formula (2), where R1 and R2, R3 and R4 in pairs form cyclohexene substituted with three methyl groups, or R1 and R3 are isobutene-2-yl radical, and R2 and R4 is a methyl radical, or R1 = R3 is 2-hydroxy-2-methylpropyl radical, and R2 = R4 is a methyl radical; and formula (3), where R1 and R2, R3 and R4, R5 and R6 in pairs form cyclohexene substituted with three methyl groups, or R1 = R3 = R5 is an isobuten-2-yl radical, and R2 = R4 = R6 is a methyl radical, or R1 = R3 = R5 is a 2-hydroxy-2-methylpropyl radical, and R2 = R4 = R6 is a methyl radical; moreover, mixtures of cyclic derivatives obtained from two and three ketone molecules, formulas (2) and (3) are selected from the following group: 3,6,9-tris(2,4,4-trimethylcyclohexene-1)spiro-1,4,7-triperoxane and 3,6-bis(2,4,4-trimethylcyclohexene-1)spiro-1,4- diperoxane; 3,6,9-triisobuten-2-yl-3,6,9-trimethyl-1,4,7-triperoxane and 3,6-diisobuten-2-yl-3,6-dimethyl-1,4-diperoxane; 3,6,9-tri(2-hydroxy-2-methylpropyl-1)-3,6,9-trimethyl-1,4,7-triperoxane and 3,6-di-(2-hydroxy-2-methylpropyl- 1)-3,6-dimethyl-1,4-diperoxane; at the following ratio of components, in % by weight: peroxyketal 0.01-0.5, diesel fraction - up to 100.
EFFECT: obtaining a fuel composition of low-sulphur diesel fuel that meets the requirements of GOST 32511, GOST R 52368, EN 590, GOST R 55475, TR CU 013/2011, as well as expanding the arsenal of using organic peroxides as ignition promoters.
3 cl, 2 tbl, 17 ex
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Authors
Dates
2023-05-12—Published
2021-12-30—Filed