FIELD: hydrocarbons.
SUBSTANCE: invention relates to a method for processing heavy hydrocarbon feedstock, including the successive passage of feedstock in the presence of hydrogen, supplied under pressure of 8-20 MPa, through a fixed catalyst bed 1 comprising aluminium oxide as a carrier, and calcium and/or magnesium compounds as an active component, having macropores with a regular spatial structure, through catalyst 2 comprising aluminium oxide as a carrier, and compounds of cobalt and/or nickel and/or molybdenum and/or tungsten as an active component, having macropores with a regular spatial structure, through catalyst 3 obtained by sulfiding a composition comprising an active ingredient and a carrier. The active component consists of a heteropoly compound containing at least one of the following compounds of the series [Co2Mo10O38H4]6-, Co3[PMo12O40]2, Ni3[PMo12O40]2, [Co(OH)6Mo6O18]3-, [Ni(OH)6Mo6O18]2-, [Ni2Mo10O38H4]6-, [Co(OH)6W6O18]3-, [PMonW12-nO40]3- (where n = 1-11), [PVnMo12-nO40](3+n)- (where n = 1-4), Mo12O30(OH)10H2[Co(H2O)3]4 or a mixture thereof and an organic additive, whereas the carrier is alumina, silicon oxide, zeolite, aluminosilicate, porous aluminophosphate, porous silicoaluminophosphate and their combination, having a regular spatial macropore structure. Further separation of gaseous products with the possibility of separating into separate oil products.
EFFECT: simultaneous involvement of raw materials in the processing without restrictions on viscosity and density, on the content of sulphur, metals and the production of oil products suitable for further processing to obtain commercial oil products without additional operations and the formation of non-recyclable residues.
10 cl, 3 tbl, 10 ex
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Authors
Dates
2023-07-20—Published
2022-06-29—Filed