FIELD: chemical industry.
SUBSTANCE: method for producing hydrogen by thermal cracking of methane with simultaneous synthesis of carbon nanotubes (CNTs) is proposed. During the cracking process, methane and hydrogen are supplied in a molar proportion of 1.15:1 with a total gas consumption not exceeding 26 moles per 100 g of catalyst. When carrying out the process, a catalyst containing 95-99 mol.% magnesium oxide is used, the rest is the metals Co and Mo in a molar ratio of 4:1. The exhaust gases are separated into methane and hydrogen and accumulated in appropriate cylinders for subsequent use. A plant for methane cracking and synthesis of carbon nanotubes is also proposed.
EFFECT: group of inventions allows to ensure a continuous cracking process producing high quality CNTs without formation of carbon dioxide.
4 cl, 2 dwg
Title | Year | Author | Number |
---|---|---|---|
METAL-OXIDE CATALYST FOR GROWING BUNDLES OF CARBON NANOTUBES FROM GASEOUS PHASE | 2010 |
|
RU2427423C1 |
CATALYST FOR SYNTHESIS OF HYDROCARBONS FROM CO AND H AND PREPARATION METHOD THEREOF | 2009 |
|
RU2414296C1 |
METHOD OF PRODUCTION OF THE CARBONIC NANOTUBES WITH THE INCAPCULATED PARTICLES OF NICKEL AND COBALT AND THE INSTALLATION FOR THE SYNTHESIS OF THE MATERIALS BASED ON THE CARBONIC NANOTUBES AND NANOPARTICLES OF NICKEL AND COBALT | 2005 |
|
RU2310601C2 |
METAL OXIDE CATALYSTS FOR GROWING CARBON NANOTUBES FROM GAS PHASE | 2009 |
|
RU2415706C1 |
HYDROCARBON SYNTHESIS CATALYST AND METHOD OF PRODUCING SAID CATALYST | 2009 |
|
RU2422200C1 |
PROCEDURE FOR FABRICATING LONG ORIENTED BRAIDS OF CARBON NANO-FIBRES | 2009 |
|
RU2393276C1 |
NANOCOMPOSITE BASED ON NITROGEN-CONTAINING CARBON NANOTUBES WITH ENCAPSULATED COBALT AND NICKEL PARTICLES AND METHOD OF OBTAINING THEREOF | 2010 |
|
RU2546154C1 |
METHOD OF OBTAINING METAL OXIDE CATALYSTS FOR GROWING CARBON NANOTUBES FROM GASEOUS PHASE | 2010 |
|
RU2476268C2 |
METHOD OF OBTAINING CARBON-METAL MATERIAL BY CATALYTIC PYROLYSIS OF ETHANOL | 2012 |
|
RU2516548C2 |
METHOD OF MAKING PRESSURE SENSOR HAVING CARBON NANOTUBES | 2012 |
|
RU2504746C1 |
Authors
Dates
2023-10-19—Published
2022-05-19—Filed