FIELD: chemistry.
SUBSTANCE: invention relates to chemical current sources and specifically to material for an oxygen-conducting solid electrolyte based on stabilized zirconium dioxide used in solid oxide fuel cells. Method of directed crystallisation of the melt in a cold container is used in the manufacture of this electrolyte. High-frequency generator with frequency of 1.76 MHz and power of 200 kW is used as a heating source. Directional crystallisation of the melt is carried out by lowering the crucible relative to the inductor at rate of 10 mm/h. Initial materials used are zirconium oxide powders, scandium and ytterbium with content of basic substance of not less than 99.99% in concentration 88–90 mol.% of ZrO2, 8–10 mol.% of Sc2O3, 1–3 mol.% of Yb2O3.
EFFECT: high energy efficiency of the fuel cell at a lower level of degradation of the solid electrolyte material.
1 cl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING SOLID ELECTROLYTE BASED ON STABILISED ZIRCONIUM DIOXIDE | 2014 |
|
RU2592936C2 |
CATHODE MATERIALS FOR SOLID OXIDE FUEL CELLS BASED ON NICKEL-CONTAINING LAYERED PEROVSKITE-LIKE OXIDES | 2013 |
|
RU2553460C2 |
CATHODE MATERIAL FOR SOFC BASED ON COPPER-CONTAINING LAYERED PEROVSKITE COMPOUNDS | 2014 |
|
RU2550816C1 |
METHOD FOR LIQUID-PHASE SYNTHESIS OF MULTI-COMPONENT CERAMIC MATERIAL IN ZrO-YO-GdO-MgO SYSTEM FOR PRODUCTION OF ELECTROLYTE FOR SOLID OXIDE FUEL CELL | 2015 |
|
RU2614322C1 |
ANODE RESISTANT TO OXIDATION-REDUCTION | 2006 |
|
RU2354013C1 |
METHOD FOR PRODUCING GAS-TIGHT SOLID OXIDE TUBULAR ELECTROLYTE FOR BASE OF SOFC | 2017 |
|
RU2681771C2 |
SOLID ELECTROLYTE BASED ON HAFNIUM OXIDE | 2012 |
|
RU2479076C1 |
TUBE ELEMENT OF ELECTROCHEMICAL DEVICE WITH THIN-LAYER SOLID-OXIDE ELECTROLYTE (VERSIONS) AND METHOD OF ITS MANUFACTURE | 2015 |
|
RU2625460C2 |
TUBULAR SOLID-OXIDE FUEL ELEMENT WITH METALLIC SUPPORT, ITS TUBULAR METALLIC POROUS BASIC LAYER AND METHODS OF THEIR PRODUCTION | 2007 |
|
RU2332754C1 |
ELECTROCHEMICAL ELEMENT AND METHOD OF ITS MANUFACTURING | 2008 |
|
RU2379670C1 |
Authors
Dates
2024-08-26—Published
2023-01-14—Filed